The effect of carbon monoxide and steam on the hydrogen permeability of a Pd/stainless steel membrane

被引：163

作者：

Li, A ^{[1
]}

Liang, W ^{[1
]}

Hughes, R ^{[1
]}

机构：

[1] Univ Salford, Dept Chem Engn, Salford M5 4WT, Lancs, England

来源：

JOURNAL OF MEMBRANE SCIENCE | 2000年 / 165卷 / 01期

关键词：

palladium membrane; carbon monoxide; steam; hydrogen permeability;

D O I：

10.1016/S0376-7388(99)00223-9

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Measurements of the hydrogen permeation rate through a Pd/stainless steel membrane have been carried out in the presence of carbon monoxide and steam and with mixtures of these two additives. Significant reductions in hydrogen permeability were observed, the extent of the reduction being dependent on the amount of CO or steam added. At low concentrations of additive(high feed flux), differences in behavior for CO and steam were noted, addition of CO at this level having little effect on hydrogen permeability, whereas addition of steam had a much more pronounced effect. (C)2000 Elsevier Science B.V. All rights reserved.

引用

页码：135 / 141

页数：7

共 21 条

[1] EFFECTS OF HIGH-CONCENTRATION CO AND CO2 ON HYDROGEN PERMEATION THROUGH THE PALLADIUM MEMBRANE [J].

AMANO, M ;

NISHIMURA, C ;

KOMAKI, M .

MATERIALS TRANSACTIONS JIM, 1990, 31 (05) :404-408

[2]

[Anonymous], PLATINUM MET REV

[3] THE EFFECT OF ADSORBED CARBON AND SULFUR ON HYDROGEN PERMEATION THROUGH PALLADIUM [J].

ANTONIAZZI, AB ;

HAASZ, AA ;

STANGEBY, PC .

JOURNAL OF NUCLEAR MATERIALS, 1989, 162 :1065-1070

[4] A study on catalytic membrane reactors for water gas shift reaction [J].

Basile, A ;

Drioli, E ;

Santella, F ;

Violante, V ;

Capannelli, G ;

Vitulli, G .

GAS SEPARATION & PURIFICATION, 1996, 10 (01) :53-61

[5] FUEL CLEANUP SYSTEM - POISONING OF PALLADIUM-SILVER MEMBRANES BY GASEOUS IMPURITIES [J].

CHABOT, J ;

LECOMTE, J ;

GRUMET, C ;

SANNIER, J .

FUSION TECHNOLOGY, 1988, 14 (02) :614-623

[6] PREPARATION AND CHARACTERIZATION OF A COMPOSITE PALLADIUM-CERAMIC MEMBRANE [J].

COLLINS, JP ;

WAY, JD .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (12) :3006-3013

[7]

HUGHES R, 1994, DEV CHEM ENG MIN PRO, V2, P105

[8] MEMBRANE REACTOR USING MICROPOROUS GLASS-SUPPORTED THIN-FILM OF PALLADIUM .1. APPLICATION TO THE WATER GAS SHIFT REACTION [J].

KIKUCHI, E ;

UEMIYA, S ;

SATO, N ;

INOUE, H ;

ANDO, H ;

MATSUDA, T .

CHEMISTRY LETTERS, 1989, (03) :489-492

[9] Preparation of Pd/ceramic composite membrane .1. Improvement of the conventional preparation technique [J].

Li, AW ;

Xiong, GX ;

Gu, JH ;

Zheng, LB .

JOURNAL OF MEMBRANE SCIENCE, 1996, 110 (02) :257-260

[10] Characterisation and permeation of palladium stainless steel composite membranes [J].

Li, AW ;

Liang, WQ ;

Hughes, R .

JOURNAL OF MEMBRANE SCIENCE, 1998, 149 (02) :259-268

← 1 2 3 →