Reductive Amination without an External Hydrogen Source

被引：101

作者：

Chusov, Denis ^{[1
]}

List, Benjamin ^{[2
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Vavilova St 28, Moscow, Russia

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 20期

关键词：

amines; amination; atom economy; carbon monoxide; reduction; TRANSITION-METAL-COMPLEXES; BORROWING HYDROGEN; HOMOGENEOUS CATALYSIS; CARBONYLATIONS; METHODOLOGY; ALCOHOLS; AMINES;

D O I：

10.1002/anie.201400059

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method of reductive amination without an external hydrogen source is reported. Carbon monoxide is used as the reductant. The reaction proceeds efficiently for a variety of carbonyl compounds and amines at low catalyst loadings and is mechanistically interesting as it does not seem to involve molecular hydrogen.

引用

页码：5199 / 5201

页数：3

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