Ring-closure reaction to novel quinoline derivatives and their structural characterization

被引:0
作者
Lü, YX
Lan, BJ
Zhou, H
Xu, W
Wang, JM
Huang, YM
机构
[1] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[3] Fudan Univ, Res Ctr Anal & Measurement, Shanghai 200433, Peoples R China
关键词
arylaldehyde; arylethylidenemalononitrile; ring closure; X-ray diffraction;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the condensation of arylaldehydes with arylethylidenemalononitriles, it was found that, besides the normal product dienes a, the ring-closure product quinoline derivatives b can be also obtained in 26%-50% yields. The substituent effects were also examined and a possible reaction mechanism was proposed for the formation of b. The X-ray crystal structure of 1b confirms the structure of the ring-closure product.
引用
收藏
页码:854 / 858
页数:5
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