Crystal structure and two-level supramolecular organization of glycinium triiodide

被引：18
|
作者：
Shestimerova, T. A. [1 ]
Bykov, M. A. [1 ]
Wei, Z. [2 ]
Dikarev, E. V. [2 ]
Shevelkov, A. V. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Bldg 3,1 Leninskie Gory, Moscow 119991, Russia
[2] SUNY Albany, Dept Chem, Albany, NY 12222 USA
来源：
RUSSIAN CHEMICAL BULLETIN | 2019年 / 68卷 / 08期
基金：
美国国家科学基金会; 俄罗斯科学基金会;
关键词：
polyiodides; crystal structure; supramolecular architecture; Raman spectroscopy; IODINE; POLYIODIDE; COMPLEXES; HYBRID;
D O I：
10.1007/s11172-019-2586-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Glycinium triiodide was synthesized and its crystal structure was determined. The crystal structure consists of alternating asymmetric triiodide anions characterized by Raman spectroscopy and glycinium cations. The cations and anions form dimers (GlyH)(2)(I-3)(2)via (N)H center dot center dot center dot O, (N)H center dot center dot center dot I, and (O)H center dot center dot center dot I hydrogen bonds. The dimers are further linked into chains by secondary I center dot center dot center dot I interactions between adjacent triiodide anions. The supramolecular structure of glycinium triiodide is discussed in comparison with polyiodides of various cations.
引用
收藏
页码：1520 / 1524
页数：5
相关论文
共 50 条
  • [41] Crystal structure and magnetic properties of two bimetallic chain compounds
    Liu, Xue-Ying
    Wang, Yi-Jun
    Jin, Kai-Hang
    Tong, Yu-Zhang
    Yang, Chun
    Wang, Qing-Lun
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2020, 67 (01) : 103 - 108
  • [42] Synthesis, Crystal Structure and Theoretical Calculations of a Three-dimensional Supramolecular Cadmium(II) Coordination Polymer
    Zhan Pei-Ying
    Wang Shao-Jie
    Li Xiu-Mei
    Pan Ya-Ru
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36 (12) : 2108 - 2114
  • [43] Synthesis, Crystal Structure and Physical Properties of a Novel Cadmium(II) Supramolecular 3D Framework
    Zhao Wei-Xing
    Wen Pu-Hong
    Wang Yan
    Jiang Luan
    Feng Guo-Dong
    Li Zong-Xiao
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (05) : 786 - 793
  • [44] Synthesis, crystal structure and photoluminescent property of a novel indium (III) supramolecular 3D framework
    Wang, Liping
    Zhang, Tianbin
    Huang, Liangliang
    Xu, Jianing
    Wang, Gang
    Zhang, Hua
    Wang, Li
    JOURNAL OF MOLECULAR STRUCTURE, 2010, 975 (1-3) : 215 - 219
  • [45] Synthesis and crystal structure of supramolecular complex of Zn(II) bridged by phthalate
    Sun, YG
    Wei, DZ
    Gao, EJ
    Ding, F
    ACTA CHIMICA SINICA, 2004, 62 (14) : 1362 - 1366
  • [46] Synthesis, crystal structure and nonlinear optical properties of a manganese supramolecular compound
    Meng, XR
    Li, LK
    Song, YL
    Zhu, Y
    Du, CX
    Fan, YT
    Hou, HW
    ACTA CHIMICA SINICA, 2001, 59 (08) : 1277 - 1282
  • [47] Syntheses and Br...π supramolecular interactions in the crystal structure of ipriflavone bromides
    Zunting Zhang
    Xiaobing Wang
    Science in China Series B: Chemistry, 2005, 48 : 315 - 325
  • [48] Analysis the UV-visible Spectra of Neuroglobin Based on Two-Level Model
    Thao, T. T.
    Anh, C. T.
    Lan, N. T.
    Viet, N. A.
    IWTCP-2 AND NCTP-39, 2015, 627
  • [49] Management Decision by Combination Two-level DEA and Kernel-based Mechanism
    Chen, Fu-Hsiang
    Zeng, Jhih-Hong
    Hsu, Ming-Fu
    Lin, Sin-Jin
    2017 JOINT 17TH WORLD CONGRESS OF INTERNATIONAL FUZZY SYSTEMS ASSOCIATION AND 9TH INTERNATIONAL CONFERENCE ON SOFT COMPUTING AND INTELLIGENT SYSTEMS (IFSA-SCIS), 2017,
  • [50] Energy transfer, correlations and decoherence in a dimer in terms of the two-level atomic distances
    Berrada, K.
    Alkaoud, A.
    QUANTUM INFORMATION PROCESSING, 2019, 18 (06)
12345