Crystal structure and two-level supramolecular organization of glycinium triiodide

被引：18

作者：

Shestimerova, T. A. ^{[1
]}

Bykov, M. A. ^{[1
]}

Wei, Z. ^{[2
]}

Dikarev, E. V. ^{[2
]}

Shevelkov, A. V. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Bldg 3,1 Leninskie Gory, Moscow 119991, Russia

[2] SUNY Albany, Dept Chem, Albany, NY 12222 USA

来源：

RUSSIAN CHEMICAL BULLETIN | 2019年 / 68卷 / 08期

基金：

美国国家科学基金会; 俄罗斯科学基金会;

关键词：

polyiodides; crystal structure; supramolecular architecture; Raman spectroscopy; IODINE; POLYIODIDE; COMPLEXES; HYBRID;

D O I：

10.1007/s11172-019-2586-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Glycinium triiodide was synthesized and its crystal structure was determined. The crystal structure consists of alternating asymmetric triiodide anions characterized by Raman spectroscopy and glycinium cations. The cations and anions form dimers (GlyH)(2)(I-3)(2)via (N)H center dot center dot center dot O, (N)H center dot center dot center dot I, and (O)H center dot center dot center dot I hydrogen bonds. The dimers are further linked into chains by secondary I center dot center dot center dot I interactions between adjacent triiodide anions. The supramolecular structure of glycinium triiodide is discussed in comparison with polyiodides of various cations.

引用

页码：1520 / 1524

页数：5

共 50 条

[31] Syntheses and Br•••π supramolecular interactions in the crystal structure of ipriflavone bromides
Zhang, ZT
Wang, XB
SCIENCE IN CHINA SERIES B-CHEMISTRY, 2005, 48 (04): : 315 - 325
[32] Synthesis, Crystal and Supramolecular Structure of {2,2′-[Ethylenedioxybis(nitrilomethylidyne)]dinaphthanolato}Cu(II)
Zhang, Yu-Jie
Zhang, Xin-Ying
Yang, Yu-Hua
Zhao, Meng-Meng
Li, Gang
Dong, Xiu-Yan
ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (09) : 2664 - 2666
[33] Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation
Gao, Hongcheng
Yu, Jiehui
Du, Juan
Niu, Huiling
Wang, Jing
Song, Xiaojing
Zhang, Wenxiang
Jia, Mingjun
JOURNAL OF CLUSTER SCIENCE, 2014, 25 (05) : 1263 - 1272
[34] A Supramolecular Dimer of Two Crystallographically Independent Co(II) Phthalate Bipyridine Complexes in One Single Crystal: Synthesis, Crystal Structure, and Thermal Studies
Gogoi, A.
Saha, U.
Dutta, D.
Bhattacharyya, M. K.
JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 60 (02) : 324 - 332
[35] A Supramolecular Dimer of Two Crystallographically Independent Co(II) Phthalate Bipyridine Complexes in One Single Crystal: Synthesis, Crystal Structure, and Thermal Studies
A. Gogoi
U. Saha
D. Dutta
M. K. Bhattacharyya
Journal of Structural Chemistry, 2019, 60 : 324 - 332
[36] Hydrothermal synthesis and crystal structure of a novel rare-earth tungsten phosphate supramolecular compound
Shu, Qi-Xia
Sun, Guo-Yuan
Wang, Xiao-Bo
Hu, Xue-Lei
INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 21 : 47 - 49
[37] Synthesis and Crystal Structure of Supramolecular Copper(II) Dimer with Asymmetric Salamo-Type Ligand
Yang, Yu-Hua
Zhang, Li-Sha
Zhang, Yu-Jie
Zhao, Meng-Meng
Li, Gang
Dong, Xiu-Yan
ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (04) : 1116 - 1118
[38] Supramolecular organization and structure of Cu(II) and Ni(II), 2,2′-bipyridine cations with tartratogermanate anions
Seifullina, Inna
Martsinko, Elena
Chebanenko, Elena
Afanasenko, Eleonora
Dyakonenko, Viktoriya
Shishkina, Svitlana
POLYHEDRON, 2019, 169 : 261 - 265
[39] Synthesis, X-ray crystal structure, and solution studies of two novel supramolecular coordination polymers of barium(II) and copper(II) based on chelidamic acid
Motieiyan, Elham
Ghadermazi, Mohammad
Nemati, Andya
Ghasemi, Nona
Silva, Manuela Ramos
Shokrollahi, Ardeshir
Arokhloo, Jeiran Karami
MONATSHEFTE FUR CHEMIE, 2013, 144 (08): : 1141 - 1151
[40] The effect of ligand substituent on crystal packing: Structural and theoretical studies of two Ga(III) supramolecular compounds
Soleimannejad, Janet
Nazarnia, Esfandiar
JOURNAL OF MOLECULAR STRUCTURE, 2016, 1116 : 207 - 217

← 1 2 3 4 5 →