Formation of cobalt nitrate hydrate, cobalt oxide, and cobalt nanoparticles using laser vaporization controlled condensation

被引:49
作者
Glaspell, GP
Jagodzinski, PW
Manivannan, A [1 ]
机构
[1] W Virginia Univ, Dept Chem, Morgantown, WV 26506 USA
[2] Colorado Sch Mines, Dept Chem & Geochem, Golden, CO 80401 USA
[3] W Virginia Univ, Dept Phys, Morgantown, WV 26506 USA
关键词
D O I
10.1021/jp0370831
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, we report for the first time the synthesis of cobalt nitrate hexahydrate, cobalt oxide, and cobalt particles formed from a high purity cobalt metal by a novel laser vaporization controlled condensation (LVCC) method under controlled pressures of N-2 and O-2. The metal vapor produced from a cobalt target in the presence of 50% N-2 and 50% O-2 results in the formation of cobalt nitrate. We also explored the possibilities of forming cobalt oxide and cobalt nanoparticles by altering the ratio of N-2 and O-2 present. For example, the synthesis of pure cobalt oxide (CoO) nanoparticles is of importance and challenging since a simple chemical route is complex. We believe that this work will be of significant importance since the present method is promising for the synthesis of metal mono oxides.
引用
收藏
页码:9604 / 9607
页数:4
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