Catalysis in electron transfer reactions: facts and mechanistic insights

被引：17
作者：
Fukuzumi, S [1 ]
机构：
[1] Osaka Univ, CREST, Japan Sci & Technol Corp, JST,Dept Mat & Life Sci, Suita, Osaka 5650871, Japan
来源：
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2002年 / 15卷 / 08期
关键词：
catalysis; electron transfer; metal ions; superoxide dismutase; oxygen; fullerene;
D O I：
10.1002/poc.496
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalysis in electron transfer reactions between electron donors and acceptors is described and the important mechanistic insight is provided by showing a number of examples of both thermal and photochemical reactions that involve metal ion-catalyzed electron transfer processes as the rate-determining steps. The quantitative measure of Lewis acidity of metal ions was obtained from the g(zz) values of ESR spectra of superoxide-metal ion complexes which vary significantly depending on the type of metal ions. Copyright (C) 2002 John Wiley Sons, Ltd.
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页码：448 / 460
页数：13
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