Catalysis in electron transfer reactions: facts and mechanistic insights

被引：17

作者：

Fukuzumi, S ^{[1
]}

机构：

[1] Osaka Univ, CREST, Japan Sci & Technol Corp, JST,Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2002年 / 15卷 / 08期

关键词：

catalysis; electron transfer; metal ions; superoxide dismutase; oxygen; fullerene;

D O I：

10.1002/poc.496

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalysis in electron transfer reactions between electron donors and acceptors is described and the important mechanistic insight is provided by showing a number of examples of both thermal and photochemical reactions that involve metal ion-catalyzed electron transfer processes as the rate-determining steps. The quantitative measure of Lewis acidity of metal ions was obtained from the g(zz) values of ESR spectra of superoxide-metal ion complexes which vary significantly depending on the type of metal ions. Copyright (C) 2002 John Wiley Sons, Ltd.

引用

页码：448 / 460

页数：13

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