Synthesis and modification of octafluoro[2.2]-paracyclophane (parylene AF4)

被引：9
作者：
Hicks, Craig [1 ]
Duffy, Brendan
Hargaden, Grainne C.
机构：
[1] Dublin Inst Technol, Focas Inst, CREST, Dublin 8, Ireland
来源：
ORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 06期
关键词：
FACILE GENERATION; BOND-CLEAVAGE; MACRO RINGS; INTERCONVERSIONS; TRIFLUOROMETHYL; CHEMISTRY;
D O I：
10.1039/c4qo00110a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Parylenes are a class of organic compounds which have gained significant attention due to their application as coatings in areas such as medical devices and electronics. This review highlights the development of synthetic pathways to Octafluoro[2.2]Paracyclophane, commonly referred to as parylene AF4. Methods which have been used to functionalise AF4 are also presented.
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收藏
页码：716 / 725
页数：10
相关论文
共 45 条
  • [1] CARBON-CARBON BOND-CLEAVAGE OF THE [2.2]PARACYCLOPHANE RADICAL-CATION GENERATED BY ELECTRON-TRANSFER OXIDATION WITH CERIUM(IV) AMMONIUM-NITRATE
    ADAM, W
    MIRANDA, MA
    MOJARRAD, F
    SHEIKH, H
    [J]. CHEMISCHE BERICHTE, 1994, 127 (05) : 875 - 879
  • [2] New C-F bond-cleavage route for the synthesis of octafluoro[2.2]paracyclophane
    Amii, H
    Hatamoto, Y
    Seo, M
    Uneyama, K
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (21) : 7216 - 7218
  • [3] 4,5-dehydro- and 4,5,15,16-bis(dehydro)octafluoro[2.2]paracyclophanes: Facile generation and extraordinary Diels-Alder reactivity
    Battiste, MA
    Duan, JX
    Zhai, YA
    Ghiviriga, I
    Abboud, KA
    Dolbier, WR
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (08) : 3078 - 3083
  • [4] 4,5-dehydrooctafluoro[2.2]paracyclophane: facile generation and extraordinary Diels-Alder reactivity
    Battiste, MA
    Duan, JX
    Zhai, YA
    Ghiviriga, I
    Abboud, KA
    Roitberg, A
    Shelton, GR
    Dolbier, WR
    [J]. TETRAHEDRON LETTERS, 2002, 43 (39) : 7047 - 7049
  • [5] Beach W. F., 1997, J ORG CHEM, V62, P7500
  • [6] PREPARATION AND STRUCTURE OF DI-P-XYLYLENE
    BROWN, CJ
    FARTHING, AC
    [J]. NATURE, 1949, 164 (4178) : 915 - 916
  • [7] FORMATION OF ARYNES BY REACTION OF POTASSIUM T-BUTOXIDE WITH ARYL HALIDES
    CADOGAN, JIG
    HALL, JKA
    SHARP, JT
    [J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (19): : 1860 - +
  • [8] SYNTHESIS OF 1,1,2,2,9,9,10,10-OCTAFLUORO 2.2!PARACYCLOPHANE
    CHOW, SW
    PILATO, LA
    WHEELWRI.WL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1970, 35 (01) : 20 - &
  • [9] Dolbier Jr W. R., 1993, EU Pat, Patent No. [0549980A1, 0549980]
  • [10] Synthesis of perfluoro[2.2]paracyclophane
    Dolbier, William R., Jr.
    Xie, Puhui
    Zhang, Lianhao
    Xu, Wei
    Chang, Ying
    Abboud, Khalil A.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (06) : 2469 - 2472
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