Metal Catalysis versus Organocatalysis in the Catalytic Asymmetric Synthesis of 3-Hydroxyoxindole

被引：29

作者：

Liu, Yunlin ^{[1
]}

Zhu, Feng ^{[1
]}

Wang, Cuihong ^{[1
]}

Zhou, Jian ^{[1
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 33卷 / 08期

基金：

中国国家自然科学基金;

关键词：

3-substituted-3-hydroxyoxindole; asymmetric catalysis; metal catalysis; organocatalysis; BAYLIS-HILLMAN REACTION; HIGHLY ENANTIOSELECTIVE SYNTHESIS; FRIEDEL-CRAFTS REACTION; ALDOL REACTION; ARYLBORONIC ACIDS; STEREOSELECTIVE-SYNTHESIS; UNACTIVATED KETONES; SUBSTITUTED ISATINS; QUATERNARY CARBON; CONVOLUTAMYDINE E;

D O I：

10.6023/cjoc201303038

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-Substituted 3-hydroxyoxindoles are widely encountered in a large number of natural products, drugs and pharmaceutically active compounds. The catalytic asymmetric construction of this privileged skeleton has attracted great attention from synthetic chemistry, and much progress has been made in recent years. This review summarizes the advances in the catalytic enantioselective synthesis of four important types of subunits of 3-substituted 3-hydroxyoxindoles, and focuses on the discussion of the differences and advantages of metal catalysis and organocatalysis.

引用

页码：1595 / 1615

页数：21

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