New Gas-Diffusion Electrode Based on Heterocyclic Microporous Polymer PIM-1 for High-Temperature Polymer Electrolyte Membrane Fuel Cell

被引：20
|
作者：
Ponomarev, I. I. [1 ]
Skupov, K. M. [1 ]
Ponomarev, Iv I. [1 ]
Razorenov, D. Yu [1 ]
Volkova, Yu A. [1 ]
Basub, V. G. [2 ,3 ]
Zhigalina, O. M. [2 ]
Bukalov, S. S. [1 ]
Volfkovich, Yu M. [4 ]
Sosenkin, V. E. [4 ]
机构：
[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
[2] Russian Acad Sci, Fed Res Ctr Crystallog & Photon, Shubnikov Inst Crystallog, Moscow 119333, Russia
[3] Kurchatov Inst, Natl Res Ctr, Moscow 123182, Russia
[4] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2019年 / 55卷 / 06期
基金：
俄罗斯科学基金会;
关键词：
intermediate temperature fuel cell; HT-PEMFC; gas-diffusion electrode; PIM-1; polymer of intrinsic microporosity; standard contact porosimetry; CARBON NANOFIBERS; POLYACRYLONITRILE; FIBER;
D O I：
10.1134/S1023193519060156
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Polymer of intrinsic microporosity PIM-1 was used for electrospun polymer nanofiber producing. After pyrolysis, the obtained nanofibers, in a form of entire mat, were used as a support for cathode electrocatalyst for high-temperature polymer electrolyte membrane fuel cell on polymer polybenzimidazole membrane. The material was characterized by the methods of standard contact porosimetry, Raman spectroscopy and scanning electron microscopy. The I-V curves for membrane-electrode assembly suggest a possibility of using the carbon material for electrodes in a fuel cell on polymer membrane.
引用
收藏
页码：552 / 557
页数：6
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