Structural characterization and tribological evaluation of quince seed mucilage

被引:42
作者
Hakala, Timo J. [1 ]
Saikko, Vesa [2 ]
Arola, Suvi [1 ,2 ]
Ahlroos, Tiina [1 ]
Helle, Aino [1 ]
Kuosmanen, Petri [2 ]
Holmberg, Kenneth [1 ]
Linder, Markus B. [1 ,2 ]
Laaksonen, Paivi [1 ,2 ]
机构
[1] VTT Tech Res Ctr Finland, FI-02044 Espoo, Finland
[2] Aalto Univ, FI-00076 Aalto, Finland
基金
芬兰科学院;
关键词
Biolubrication; Boundary lubrication; Macromolecules; Biomimetics; SYNOVIAL JOINT LUBRICATION; PLANT-CELL WALL; CELLULOSE-GLUCURONOXYLANS; NANOFIBRILLATED CELLULOSE; AQUEOUS LUBRICATION; PROTEINS; SURFACES; NANOCOMPOSITES; BEHAVIOR;
D O I
10.1016/j.triboint.2014.04.018
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
The mucilage, originating from the seeds of quince fruit was characterized as a potential bio-inspired water-based lubricant. The mucilage consists mainly of fine cellulose nanofibrils and charged hemicelluloses whose structure and properties were characterized here by atomic force microscopy (AFM) and tribological Pin-On-Disc (POD) experiments. The hemicellulose-decorated nanocellulose fibrils were 3.0 +/- 0.7 nm in thickness, had a very large aspect ratio and also had a tendency to self-align when dried on mica surface. Macroscale tribological tests showed that the mucilage was able to reduce the coefficient of friction of polyethylene/stainless steel contact to values below 0.03. Thus, we show that quince mucilage is a native nanocellulose material with a notable ability to lower friction. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:24 / 31
页数:8
相关论文
共 32 条
[1]   Biomimetic Principles in Polymer and Material Science [J].
Antonietti, Markus ;
Fratzl, Peter .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (02) :166-170
[2]   The role of hemicellulose in nanofibrillated cellulose networks [J].
Arola, Suvi ;
Malho, Jani-Markus ;
Laaksonen, Paivi ;
Lille, Martina ;
Linder, Markus B. .
SOFT MATTER, 2013, 9 (04) :1319-1326
[3]   Biomimetic lubrication [J].
Dedinaite, Andra .
SOFT MATTER, 2012, 8 (02) :273-284
[4]   Review: current international research into cellulose nanofibres and nanocomposites [J].
Eichhorn, S. J. ;
Dufresne, A. ;
Aranguren, M. ;
Marcovich, N. E. ;
Capadona, J. R. ;
Rowan, S. J. ;
Weder, C. ;
Thielemans, W. ;
Roman, M. ;
Renneckar, S. ;
Gindl, W. ;
Veigel, S. ;
Keckes, J. ;
Yano, H. ;
Abe, K. ;
Nogi, M. ;
Nakagaito, A. N. ;
Mangalam, A. ;
Simonsen, J. ;
Benight, A. S. ;
Bismarck, A. ;
Berglund, L. A. ;
Peijs, T. .
JOURNAL OF MATERIALS SCIENCE, 2010, 45 (01) :1-33
[5]  
Feix R, 1935, GB424305
[6]   Fine structure in cellulose microfibrils:: NMR evidence from onion and quince [J].
Ha, MA ;
Apperley, DC ;
Evans, BW ;
Huxham, M ;
Jardine, WG ;
Viëtor, RJ ;
Reis, D ;
Vian, B ;
Jarvis, MC .
PLANT JOURNAL, 1998, 16 (02) :183-190
[7]   Adhesion and tribological properties of hydrophobin proteins in aqueous lubrication on stainless steel surfaces [J].
Hakala, Timo J. ;
Laaksonen, Paivi ;
Saikko, Vesa ;
Ahlroos, Tiina ;
Helle, Aino ;
Mahlberg, Riitta ;
Haehl, Hendrik ;
Jacobs, Karin ;
Kuosmanen, Petri ;
Linder, Markus B. ;
Holmberg, Kenneth .
RSC ADVANCES, 2012, 2 (26) :9867-9872
[8]   Influence of Salt on the Aqueous Lubrication Properties of End-Grafted, Ethylene Glycol-Based Self-Assembled Monolayers [J].
Heeb, Raphael ;
Lee, Seunghwan ;
Venkataraman, Nagaiyanallur V. ;
Spencer, Nicholas D. .
ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (05) :1105-1112
[9]  
Ioelovich M., 2008, Current Trends in Polymer Science, V12, P43