Lamellar-crossing-structured Ni(OH)2/CNTs/Ni(OH)2 nanocomposite for electrochemical supercapacitor materials

被引:28
作者
Wu, Qingnan [1 ]
Wen, Ming [1 ,2 ]
Chen, Shipei [1 ]
Wu, Qingsheng [1 ,2 ]
机构
[1] Tongji Univ, State Key Lab Pollut Control & Resource Reuse, Dept Chem, Shanghai 200092, Peoples R China
[2] Tongji Univ, Shanghai Key Lab Chem Assessment & Sustainabil, Shanghai 200092, Peoples R China
基金
中国国家自然科学基金;
关键词
Ni(OH)(2)/CNTs/Ni(OH)(2) nanocomposite; Lamellar-crossing-nanostructure; Supercapacitor; Pseudocapacitor electrode material; HIGH-ENERGY DENSITY; CARBON NANOTUBES; ELECTRODE MATERIAL; NANOSTRUCTURES; NANOPARTICLES; FABRICATION; NANOFLAKES; COMPOSITE; RUO2;
D O I
10.1016/j.jallcom.2015.05.227
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ni(OH)(2)/CNTs/Ni(OH)(2) lamellar-crossing-nanostructure with a single lamellar spacing of similar to 5 nm was effectively constructed through two-phase-interface reaction process followed by the CNTs crossed among the lamellar-nanostructured Ni(OH)(2). The resultant nanocomposite can offer large active surface areas and short diffusion paths for electrons and ions, and is investigated as a potential pseudocapacitor electrode material for electrochemical energy storage applications. Electrochemical data demonstrate that the as-prepared nanocomposite exhibits a high specific capacitance of similar to 1600 F g(-1) at the scan rate of 1 mV s(-1) in 6 M KOH solution at normal pressure and temperature, which is great higher than Ni(OH)(2) (similar to 1200 F g(-1)). Furthermore, Ni(OH)(2)/CNTs/Ni(OH)(2) nanocomposite shows a higher energy density (similar to 125 Wh kg(-1), 2 A g(-1)) and has a slightly decrease of 5% in specific capacitance after 1000 continuous charge/discharge cycles. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:990 / 997
页数:8
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