Synthesis and characterization of epoxy-acrylic polymer on the basis of 2-hydroxy-3-para-nonylphenoxy-propyl acrylate

被引：8

作者：

Rosu, D ^{[1
]}

Cascaval, CN ^{[1
]}

Mustata, F ^{[1
]}

Mija, A ^{[1
]}

机构：

[1] PETRU PONI INST MACROMOLEC CHEM,R-6600 IASI,ROMANIA

来源：

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 1996年 / 35卷 / 03期

关键词：

D O I：

10.1080/03602559608000929

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(2-hydroxy-3-para-nonylphenoxy-propyl acrylate) polymer was synthesized in solution and in bulk by radical polymerization of 2-hydroxy-3-para-nonylphenoxy-propyl acrylate monomer. The polymer obtained in solution is soluble in various organic solvents. It was characterized by IR and H-1-NMR spectroscopy, cryoscopy, and viscometric behavior. The polymer synthesized in bulk is insoluble. It was characterized by IR spectroscopy and by solubility parameter. The number-average molecular weight of the soluble polymer is around 3100 and the intrinsic viscosity measured in cyclohexane at 25 degrees C +/- 0.05 is 2.8 x 10(-2) dL/g. The polymer has a non-Newtonian rheological behavior of pronounced pseudoplastic type. The insoluble polymer has the solubility parameter 9.2 (cal/mL)(1/2).

引用

页码：417 / 426

页数：10

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