Recent advances and perspectives in copper-catalyzed Sonogashira coupling reactions

被引：181

作者：

Thomas, Anns Maria ^{[1
]}

Sujatha, Asha ^{[1
]}

Anilkumar, Gopinathan ^{[1
]}

机构：

[1] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam 686560, Kerala, India

来源：

RSC ADVANCES | 2014年 / 4卷 / 42期

关键词：

PALLADIUM-FREE; ARYL IODIDES; TERMINAL ALKYNES; HETEROARYL HALIDES; CONJUGATED ENYNES; VINYL IODIDES; SOLVENT-FREE; LIGAND-FREE; ACETYLENES; DERIVATIVES;

D O I：

10.1039/c4ra02529f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C-C bond formation using transition metal catalyzed Sonogashira coupling reaction is an indispensable tool in synthetic organic chemistry. Initially Pd complexes were used as catalysts; however advances in catalyst design fuelled the development of Cu catalysts, which are cheaper and more environmentally benign than the Pd complexes. This is the first review reported so far dealing exclusively with Cu-catalyzed Sonogashira coupling reactions. This review illustrates the current strategies and potential of Cu-catalyzed Sonogashira coupling reactions.

引用

页码：21688 / 21698

页数：11

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