Coordination-Driven Polymerization of Supramolecular Nanocages

被引：82
作者：
Niu, Zheng [1 ,2 ,3 ]
Fang, Sheng [1 ,2 ]
Liu, Xiao [1 ,2 ]
Ma, Jian-Gong [1 ,2 ]
Ma, Shengqian [3 ]
Cheng, Peng [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, Key Lab Adv Energy Mat Chem MOE, Tianjin 300071, Peoples R China
[2] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
[3] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 47期
关键词：
METAL-ORGANIC POLYHEDRA; PORE-SIZE; CAGES; DISCRETE; FRAMEWORKS; SUPERCONTAINERS; NANOSTRUCTURES; TRANSFORMATION; CONVERSION; ASSEMBLIES;
D O I：
10.1021/jacs.5b10815
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Controlled assembly of OD supramolecular nanocages into 2D or 3D architectures has been demonstrated for the first time via a coordination-driven polymerization approach, and the conversion from a 2D to 3D supramolecular architecture has also been successfully achieved via a temperature-induced crystal transformation. The boost of dimensionality for the supramolecular architecture has led to steady yet remarkable enhancement of properties, as reflected from the gas adsorption studies.
引用
收藏
页码：14873 / 14876
页数：4
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