Coordination-Driven Polymerization of Supramolecular Nanocages

被引：82

作者：

Niu, Zheng ^{[1
,2
,3
]}

Fang, Sheng ^{[1
,2
]}

Liu, Xiao ^{[1
,2
]}

Ma, Jian-Gong ^{[1
,2
]}

Ma, Shengqian ^{[3
]}

Cheng, Peng ^{[1
,2
]}

机构：

[1] Nankai Univ, Dept Chem, Key Lab Adv Energy Mat Chem MOE, Tianjin 300071, Peoples R China

[2] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China

[3] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 47期

关键词：

METAL-ORGANIC POLYHEDRA; PORE-SIZE; CAGES; DISCRETE; FRAMEWORKS; SUPERCONTAINERS; NANOSTRUCTURES; TRANSFORMATION; CONVERSION; ASSEMBLIES;

D O I：

10.1021/jacs.5b10815

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlled assembly of OD supramolecular nanocages into 2D or 3D architectures has been demonstrated for the first time via a coordination-driven polymerization approach, and the conversion from a 2D to 3D supramolecular architecture has also been successfully achieved via a temperature-induced crystal transformation. The boost of dimensionality for the supramolecular architecture has led to steady yet remarkable enhancement of properties, as reflected from the gas adsorption studies.

引用

页码：14873 / 14876

页数：4

共 55 条

[1] Hydroxylated nanoballs: synthesis, crystal structure, solubility and crystallization on surfaces [J].

Abourahma, H ;

Coleman, AW ;

Moulton, B ;

Rather, B ;

Shahgaldian, P ;

Zaworotko, MJ .

CHEMICAL COMMUNICATIONS, 2001, (22) :2380-2381

[2] Metal-organic molecular cages: applications of biochemical implications [J].

Ahmad, Nazir ;

Younus, Hussein A. ;

Chughtai, Adeel H. ;

Verpoort, Francis .

CHEMICAL SOCIETY REVIEWS, 2015, 44 (01) :9-25

[3] Discrete metal-carboxylate self-assembled cages: Design, synthesis and applications [J].

Ahmad, Nazir ;

Chughtai, Adeel H. ;

Younus, Hussein A. ;

Verpoort, Francis .

COORDINATION CHEMISTRY REVIEWS, 2014, 280 :1-27

[4]

ALKORDI MH, 2011, ANGEW CHEM INT EDIT, V2, P1695, DOI DOI 10.1039/C1SC00269D

[5] High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].

An, Jihyun ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+

[6] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[7] Electrospinning: designed architectures for energy conversion and storage devices [J].

Cavaliere, Sara ;

Subianto, Surya ;

Savych, Iuliia ;

Jones, Deborah J. ;

Roziere, Jacques .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (12) :4761-4785

[8] Controllable Coordination-Driven Self-Assembly: From Discrete Metallocages to Infinite Cage-Based Frameworks [J].

Chen, Lian ;

Chen, Qihui ;

Wu, Mingyan ;

Jiang, Feilong ;

Hong, Maochun .

ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (02) :201-210

[9] Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination [J].

Cook, Timothy R. ;

Stang, Peter J. .

CHEMICAL REVIEWS, 2015, 115 (15) :7001-7045

[10] Modular Assembly of Metal-Organic Supercontainers Incorporating Sulfonylcalixarenes [J].

Dai, Feng-Rong ;

Wang, Zhenqiang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (19) :8002-8005

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