Coordination-Driven Polymerization of Supramolecular Nanocages

被引：82
作者：
Niu, Zheng [1 ,2 ,3 ]
Fang, Sheng [1 ,2 ]
Liu, Xiao [1 ,2 ]
Ma, Jian-Gong [1 ,2 ]
Ma, Shengqian [3 ]
Cheng, Peng [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, Key Lab Adv Energy Mat Chem MOE, Tianjin 300071, Peoples R China
[2] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
[3] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 47期
关键词：
METAL-ORGANIC POLYHEDRA; PORE-SIZE; CAGES; DISCRETE; FRAMEWORKS; SUPERCONTAINERS; NANOSTRUCTURES; TRANSFORMATION; CONVERSION; ASSEMBLIES;
D O I：
10.1021/jacs.5b10815
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Controlled assembly of OD supramolecular nanocages into 2D or 3D architectures has been demonstrated for the first time via a coordination-driven polymerization approach, and the conversion from a 2D to 3D supramolecular architecture has also been successfully achieved via a temperature-induced crystal transformation. The boost of dimensionality for the supramolecular architecture has led to steady yet remarkable enhancement of properties, as reflected from the gas adsorption studies.
引用
收藏
页码：14873 / 14876
页数：4
相关论文
共 55 条
  • [1] Hydroxylated nanoballs: synthesis, crystal structure, solubility and crystallization on surfaces
    Abourahma, H
    Coleman, AW
    Moulton, B
    Rather, B
    Shahgaldian, P
    Zaworotko, MJ
    [J]. CHEMICAL COMMUNICATIONS, 2001, (22) : 2380 - 2381
  • [2] Metal-organic molecular cages: applications of biochemical implications
    Ahmad, Nazir
    Younus, Hussein A.
    Chughtai, Adeel H.
    Verpoort, Francis
    [J]. CHEMICAL SOCIETY REVIEWS, 2015, 44 (01) : 9 - 25
  • [3] Discrete metal-carboxylate self-assembled cages: Design, synthesis and applications
    Ahmad, Nazir
    Chughtai, Adeel H.
    Younus, Hussein A.
    Verpoort, Francis
    [J]. COORDINATION CHEMISTRY REVIEWS, 2014, 280 : 1 - 27
  • [4] ALKORDI MH, 2011, ANGEW CHEM INT EDIT, V2, P1695, DOI DOI 10.1039/C1SC00269D
  • [5] High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores
    An, Jihyun
    Geib, Steven J.
    Rosi, Nathaniel L.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) : 38 - +
  • [6] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
    Banerjee, Rahul
    Furukawa, Hiroyasu
    Britt, David
    Knobler, Carolyn
    O'Keeffe, Michael
    Yaghi, Omar M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) : 3875 - +
  • [7] Electrospinning: designed architectures for energy conversion and storage devices
    Cavaliere, Sara
    Subianto, Surya
    Savych, Iuliia
    Jones, Deborah J.
    Roziere, Jacques
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (12) : 4761 - 4785
  • [8] Controllable Coordination-Driven Self-Assembly: From Discrete Metallocages to Infinite Cage-Based Frameworks
    Chen, Lian
    Chen, Qihui
    Wu, Mingyan
    Jiang, Feilong
    Hong, Maochun
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (02) : 201 - 210
  • [9] Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination
    Cook, Timothy R.
    Stang, Peter J.
    [J]. CHEMICAL REVIEWS, 2015, 115 (15) : 7001 - 7045
  • [10] Modular Assembly of Metal-Organic Supercontainers Incorporating Sulfonylcalixarenes
    Dai, Feng-Rong
    Wang, Zhenqiang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (19) : 8002 - 8005
123456