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Thermodynamic and transport properties of 2-methoxyaniline with substituted ethanols at various temperatures
被引:2
作者:
Mukesh, B.
[1
]
Sreekanth, T.
[2
]
Krishna, T. Srinivasa
[3
]
Gowrisankar, M.
[4
]
机构:
[1] Vignan Inst Technol & Sci, Dept Phys, Deshmukhi, India
[2] JNTUH Coll Engn Sulthanpur, Dept Phys, Medak, India
[3] PB Siddhartha Coll Arts & Sci, Dept Phys, Vijayawada, India
[4] JKCC Acharya Nagarjuna Univ, Dept Chem, Guntur, India
关键词:
Density;
speed of sound;
viscosity;
2-methoxyaniline;
substituted ethanol;
FT-IR spectra;
EXCESS MOLAR VOLUMES;
BINARY-MIXTURES;
REFRACTIVE-INDEX;
HEAT-CAPACITIES;
SPECTROSCOPIC PROPERTIES;
ATMOSPHERIC-PRESSURE;
CYCLIC ETHERS;
VISCOSITY;
DENSITY;
SYSTEM;
D O I:
10.1080/01430750.2019.1636873
中图分类号:
TE [石油、天然气工业];
TK [能源与动力工程];
学科分类号:
0807 ;
0820 ;
摘要:
Densities (rho), the speed of sound (u) and viscosities (eta) accounted for binary liquid combinations of 2-methoxyaniline with substituted ethanols (2-phenylethanol, 2-chloroethanol and 2-aminoethanol) over the whole arrangement scope of mole fraction at T = 303.15-318.15 K and at ambient pressure were measured. The excess and variable functions have been computed from the measured basic data. Excess and deviation functions have been correlated utilising the Redlich-Kister third-order polynomial equation. The excess partial functions have been figured for the binary systems all through the creation go and at infinite dilutions. The interpretations of these properties with the arrangement of investigated systems suggest the loss of dipolar association, deviation in size and fabrication of the segment molecules and hydrogen bonding between 2-methoxyaniline with substituted ethanols. V-E comes out have been anatomised on the part of Prigogine-Flory-Patterson theory.
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页码:425 / 434
页数:10
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