Synthesis and characterization of ordered mesoporous anion-exchange inorganic/organic hybrid resins for radionuclide separation

被引：73

作者：

Ju, YH

Webb, OF

Dai, S

Lin, JS

Barnes, CE

机构：

[1] Oak Ridge Natl Lab, Chem Technol Div, Oak Ridge, TN 37831 USA

[2] Oak Ridge Natl Lab, Solid Sate Div, Oak Ridge, TN 37831 USA

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2000年 / 39卷 / 02期

关键词：

D O I：

10.1021/ie990597v

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Ordered mesoporous anion-exchange hybrid resin materials were prepared by hydrolysis synthesis using the micellar template approach. The prepared samples were characterized via infrared spectroscopy, nitrogen sorption, and small-angle X-ray scattering. The uptakes of anionic thorium nitrate complexes by the new resins in 8 N nitric acid solutions were determined. The thorium loading capacity of the hybrid mesoporous silica functionalized with N-trimethoxysilylpropyl-N,N,N-tri-n-butylammonium is greater than that of the hybrid mesoporous silica functionalized with N-trimethoxylsilylpropyl-N,N,N-trimethylammonium The mesoporous hybrid anion-exchange resins were shown to be much more selective than a popular organic commercial anion-exchange resin.

引用

页码：550 / 553

页数：4

共 31 条

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