Atomic structure of Zr-Cu glassy alloys and detection of deviations from ideal solution behavior with Al addition by x-ray diffraction using synchrotron light in transmission

被引:57
作者
Georgarakis, K. [1 ,2 ]
Yavari, A. R. [1 ,2 ,3 ]
Louzguine-Luzgin, D. V. [2 ]
Antonowicz, J. [4 ]
Stoica, M. [5 ]
Li, Y. [1 ]
Satta, M. [1 ]
LeMoulec, A. [1 ]
Vaughan, G. [3 ]
Inoue, A. [2 ]
机构
[1] Inst Natl Polytech Grenoble, CNRS, Euronano SIMaP, F-38402 St Martin Dheres, France
[2] Tohoku Univ, WPI AIMR, Aoba Ku, Sendai, Miyagi 9808577, Japan
[3] European Synchrotron Radiat Facil, F-38042 Grenoble, France
[4] Warsaw Univ Technol, Fac Phys, PL-00662 Warsaw, Poland
[5] IFW Dresden, Inst Complex Mat, D-01171 Dresden, Germany
关键词
aluminium alloys; copper alloys; glass structure; metallic glasses; vitreous state; X-ray diffraction; zirconium alloys; METALLIC GLASSES; AMORPHOUS-ALLOYS; FORMING ALLOYS; SCIENCE;
D O I
10.1063/1.3136428
中图分类号
O59 [应用物理学];
学科分类号
摘要
The atomic structure of Zr-Cu binary amorphous alloys was studied using real space pair distribution functions derived from x-ray diffraction. The structure can be modeled by an ideal solution approximation because of relatively weak Cu-Zr atomic interactions. Addition of Al to Zr-Cu metallic glasses modifies the atomic structure in the short and medium range order because of the strongly attractive interaction between Al and Zr atoms. These interactions generate strong deviations from the ideal solution behavior.
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页数:3
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