Improved fouling resistance for RO membranes by a surface modification method

被引:10
|
作者
Park, Hee Min [1 ]
Yoo, Jin [2 ]
Lee, Yong Taek [1 ]
机构
[1] Kyung Hee Univ, Coll Engn, Dept Chem Engn, Namyangju Si 446701, Gyeonggi Do, South Korea
[2] Samyang Corp, Chem R&D Ctr, Tech Ctr, Daedeok Daero 730, Daejeon 34055, South Korea
关键词
Polyamide; Reverse osmosis membrane; Surface modification; Silane coupling agents; Fouling resistance; REVERSE-OSMOSIS MEMBRANES; SILANE COUPLING AGENTS; ULTRAFILTRATION MEMBRANES; POLYAMIDE RO; GRAPHENE; PERFORMANCE; CHEMISTRY; LAYER;
D O I
10.1016/j.jiec.2019.03.059
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We investigated the surface modification of reverse osmosis (RO) membranes to enhance fouling resistance. RO membranes were modified via a sol-gel process using aminopropyltrimethoxysilane (APTMS), chlorotrimethoxysilane (CTMS) and mercaptopropyltrimethoxysilane (MPTMS). The fouling test showed that the flux of the pristine decreased continuously from 52.3 to 20 GFD, whereas APTMS-RO, CTMS-RO and MPTMS-RO were maintained about 37, 25, and 13 GFD, respectively. Salt rejection was maintained over 97.4%. The FRR values of pristine, APTMS-RO, CTMS-RO, and MPTMS-RO were 75.5, 98, 92.2, 88.3%, after chemical cleaning process. As a result, the modified RO membranes have excellent antifouling properties after 3-cycles chemical cleaning. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:344 / 354
页数:11
相关论文
共 50 条
  • [21] Polymeric membranes: Surface modification for minimizing (bio)colloidal fouling
    Kochkodan, Victor
    Johnson, Daniel J.
    Hilal, Nidal
    ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2014, 206 : 116 - 140
  • [22] Surface modification of UF membranes with functionalized MWCNTs to control membrane fouling by NOM fractions
    Bai, Langming
    Liang, Heng
    Crittenden, John
    Qu, Fangshu
    Ding, An
    Ma, Jun
    Du, Xing
    Guo, Shaodong
    Li, Guibai
    JOURNAL OF MEMBRANE SCIENCE, 2015, 492 : 400 - 411
  • [23] Enhancement in permselectivity and antibacterial performances of polyamide RO membranes via surface modification of AgCl nanoparticles
    Li, Hao
    Cheng, Dongbing
    Dong, Lingyao
    Qian, Feng
    DESALINATION AND WATER TREATMENT, 2018, 116 : 19 - 28
  • [24] Novel RO membranes fabricated by grafting sulfonamide group: Improving water permeability, fouling resistance and chlorine resistant performance
    Wang, Juntao
    Li, Shao-Lu
    Guan, Yaxu
    Zhu, Can
    Gong, Genghao
    Hu, Yunxia
    JOURNAL OF MEMBRANE SCIENCE, 2022, 641
  • [25] Surface modification of thin-film composite polyamide reverse osmosis membranes with thermo-responsive polymer (TRP) for improved fouling resistance and cleaning efficiency
    Yu, Sanchuan
    Liu, Xuesong
    Liu, Jingqun
    Wu, Dihua
    Liu, Meihong
    Gao, Congjie
    SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 76 (03) : 283 - 291
  • [26] Surface Modification of RO Desalination Membrane Using ZnO Nanoparticles of Different Morphologies to Mitigate Fouling
    Rajakumaran, Revathy
    Vinisha, Boddu
    Kumar, Mathava
    Chetty, Raghuram
    FRONTIERS IN WATER-ENERGY-NEXUS NATURE-BASED SOLUTIONS, ADVANCED TECHNOLOGIES AND BEST PRACTICES FOR ENVIRONMENTAL SUSTAINABILITY, 2020, : 183 - 185
  • [27] In Situ Surface Chemical Modification of Thin-Film Composite Forward Osmosis Membranes for Enhanced Organic Fouling Resistance
    Lu, Xinglin
    Castrillon, Santiago Romero-Vargas
    Shaffer, Devin L.
    Ma, Jun
    Elimelech, Menachem
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2013, 47 (21) : 12219 - 12228
  • [28] Improving fouling resistance and chlorine stability of aromatic polyamide thin-film composite RO membrane by surface grafting of polyvinyl alcohol (PVA)
    Liu, Meihong
    Chen, Qjng
    Wang, Lizhong
    Yu, Sanchuan
    Gao, Congjie
    DESALINATION, 2015, 367 : 11 - 20
  • [29] A facile method for polyamide membrane modification by poly(sulfobetaine methacrylate) to improve fouling resistance
    Zhang, Yang
    Wang, Zhen
    Lin, Weifeng
    Sun, Haotian
    Wu, Liguang
    Chen, Shengfu
    JOURNAL OF MEMBRANE SCIENCE, 2013, 446 : 164 - 170
  • [30] Fouling control through the hydrophilic surface modification of poly(vinylidene fluoride) membranes
    Jang, Hanna
    Song, Du-Hyun
    Kim, In-Chul
    Kwon, Young-Nam
    JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (21)