Phosphine gold(I)-catalyzed hydroamination of alkenes under thermal and microwave-assisted conditions

被引:242
作者
Liu, Xin-Yuan
Li, Cheng-Hui
Che, Chi-Ming
机构
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, Open Lab Chem Biol, Inst Mol Technol Drug Discovery & Synth, Hong Kong, Hong Kong, Peoples R China
关键词
D O I
10.1021/ol060719x
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Phosphine gold(I) complexes catalyzed isomerization of terminal alkenes and hydroamination of unactivated alkenes under thermal and microwave-assisted conditions. This is the first example of the use of microwave radiation as a heat source for gold(I)-catalyzed organic reactions.
引用
收藏
页码:2707 / 2710
页数:4
相关论文
共 60 条
[1]   Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: A dramatic effect of counteranions on reaction efficiency [J].
Anderson, LL ;
Arnold, J ;
Bergman, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (42) :14542-14543
[2]   Highly efficient access to strained bicyclic ketals via gold-catalyzed cycloisomerization of bis-homopropargylic diols [J].
Antoniotti, S ;
Genin, E ;
Michelet, V ;
Genêt, JP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (28) :9976-9977
[3]   Recent applications of gold catalysis in organic synthesis [J].
Arcadi, A ;
Di Giuseppe, S .
CURRENT ORGANIC CHEMISTRY, 2004, 8 (09) :795-812
[4]  
BOWMAN WC, 1979, TXB PHARM, pCH34
[5]   Efficient gold-catalyzed hydroamination of 1,3-dienes [J].
Brouwer, C ;
He, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (11) :1744-1747
[6]  
Brunet J.J., 2001, CATALYTIC HETEROFUNC, P91
[7]  
Bytschkov I, 2003, EUR J ORG CHEM, V2003, P935
[8]   Synthesis of cyclic sulfonamides via intramolecular copper-catalyzed reaction of unsaturated iminoiodinanes [J].
Dauban, P ;
Dodd, RH .
ORGANIC LETTERS, 2000, 2 (15) :2327-2329
[9]   Gold-catalyzed intramolecular reaction of indoles with alkynes: Facile formation of eight-membered rings and an unexpected allenylation [J].
Ferrer, C ;
Echavarren, AM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (07) :1105-1109
[10]   EFFECTIVE TRANSFORMATION OF UNACTIVATED ALKYNES INTO KETONES OR ACETALS BY MEANS OF AU(III) CATALYST [J].
FUKUDA, Y ;
UTIMOTO, K .
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (11) :3729-3731