Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa

被引：29

作者：

Mokbel, Ilham ^{[1
]}

Razzouk, Antonio ^{[1
]}

Sawaya, Terufat ^{[1
]}

Jose, Jacques ^{[1
]}

机构：

[1] Univ Lyon 1, Sci Analyt Lab, UMR 5180, Equipe Thermodynam & Anal, F-69622 Villeurbanne, France

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2009年 / 54卷 / 03期

关键词：

ENTHALPY; VAPORIZATION; SOLUBILITY; PARTITION; CAPTURE; SYSTEMS;

D O I：

10.1021/je800603z

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In this study, we reported experimental vapor pressures of several amines presenting different molecular structures, 2-phenylethylamine, benzylamine, triethylamine and cis-2,6-dimethylpiperidine, using a static apparatus. The pressure range is comprised between 0.2 Pa and 75 kPa, and the temperature range is between (273 and 365) K. From the temperature dependence of the vapor pressures, the molar enthalpies of vaporization at the mean temperature of the experimental range were derived from the Clausius-Clapeyron equation. From these results, the standard enthalpies of vaporization at T = 298.15 K were calculated and compared with the open literature values.

引用

页码：819 / 822

页数：4

共 17 条

[1] ENTHALPY OF FORMATION OF BENZYLAMINE [J].

CARSON, AS ;

LAYE, PG ;

YUREKLI, M .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1977, 9 (09) :827-829

[2] Enthalpies of vaporization of organic and organometallic compounds, 1880-2002 [J].

Chickos, JS ;

Acree, WE .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 2003, 32 (02) :519-878

[3] Combined experimental and computational study of the thermochemistry of methylpiperidines [J].

da Silva, MAVR ;

Cabral, JITA ;

Gomes, P ;

Gomes, JRB .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (10) :3677-3685

[4]

Daubert T. E., 1991, DIPPR DATA SERIES, V1, P80

[5] VAPOR-PRESSURE OF TRIMETHYL PHOSPHITE AND TRIETHYLAMINE [J].

DUTT, NVK ;

KAHOL, AP ;

JYOTHIRAJU, P .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1982, 27 (04) :369-370

[6] THERMODYNAMIC PROPERTIES OF BINARY AND TERNARY-SYSTEMS - VAPOR LIQUID EQUILIBRIUM DATA IN THE TRIETHYLAMINE + TOLUENE SYSTEM [J].

KOKKONEN, P ;

ARVOLA, H .

THERMOCHIMICA ACTA, 1984, 77 (1-3) :333-339

[7] Selection of new absorbents for carbon dioxide capture [J].

Ma'mun, Sholeh ;

Svendsen, Hallvard F. ;

Hoff, Karl A. ;

Juliussen, Olav .

ENERGY CONVERSION AND MANAGEMENT, 2007, 48 (01) :251-258

[8] ENTHALPY DATA OF LIQUIDS .16. TEMPERATURE-DEPENDENCE OF HEATS OF VAPORIZATION, SATURATED VAPOR-PRESSURES AND COHESIVE ENERGIES FOR A GROUP OF AMINES [J].

MAJER, V ;

SVOBODA, V ;

KOUBEK, J ;

PICK, J .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1979, 44 (12) :3521-3528

[9]

Majer V., 1985, ENTHALPIES VAPORIZAT, P300

[10] Simulation of enthalpy and capacity of CO2 absorption by aqueous amine systems [J].

McCann, Nichola ;

Maeder, Marcel ;

Attalla, Moetaz .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (06) :2002-2009

← 1 2 →