Isopiestic studies on the systems {NaCl plus BaCl2 plus mannitol(sat) (aq)} and {KCl plus glycine plus mannitol(sat) (aq)} at the temperature 298.15 K

被引:7
作者
Hu, YF [1 ]
Liu, YH
Sun, SP
机构
[1] Univ Petr, High Pressure Fluid Phase Behav & Property Res La, Beijing, Peoples R China
[2] Northeastern Univ, Dept Chem, Shenyang 110006, Peoples R China
关键词
isopiestic studies; linear isopiestic relations; NaCl; KCl; BaCl2; glycine; mannitol;
D O I
10.1006/jcht.1999.0597
中图分类号
O414.1 [热力学];
学科分类号
摘要
Isopiestic measurements have been made for the systems (NaCl + BaCl2 + mannitol((sat))(aq)} and (KCl + glycine + mannitol((sat))(aq)} at T = 298.15 K. The results agree well with the linear relations for the saturated systems published previously and indicate that if the unsaturated subsystem ((B + C)(aq), where B and C represent the unsaturated solutes} conforms to Zdanovskii's rule and the Stokes and Robinson relation, then the saturated system {(B + C + A(2(sat)))(aq), where A(2) denotes the saturated solute) obeys the relations for the saturated systems. (C) Academic Press.
引用
收藏
页码:341 / 347
页数:7
相关论文
共 18 条
[1]  
[Anonymous], 1965, ELECT SOLUTIONS
[2]   THERMODYNAMICS OF TERNARY SYSTEM - WATER-GLYCINE-POTASSIUM CHLORIDE AT 25 DEGREES C FROM VAPOR PRESSURE MEASUREMENTS [J].
BOWER, VE ;
ROBINSON, RA .
JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1965, A 69 (02) :131-+
[3]   ISOPIESTIC VAPOR PRESSURE MEASUREMENTS OF TERNARY SYSTEM - SORBITOL-SODIUM CHLORIDE-WATER AT 25 DEGREES [J].
BOWER, VE ;
ROBINSON, RA .
JOURNAL OF PHYSICAL CHEMISTRY, 1963, 67 (07) :1540-&
[4]   GENERAL METHOD OF PREDICTING WATER ACTIVITY OF TERNARY AQUEOUS-SOLUTIONS FROM BINARY DATA [J].
CHEN, H ;
SANGSTER, J ;
TENG, TT ;
LENZI, F .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1973, 51 (02) :234-241
[5]   Isopiestic determination of osmotic coefficients and evaluation of activity coefficients of aqueous mixtures of sodium and potassium chloride at 45 degrees C [J].
Flesia, MA ;
deChialvo, MRG ;
Chialvo, AC .
FLUID PHASE EQUILIBRIA, 1997, 131 (1-2) :189-196
[6]   Isopiestic studies on (mannitol plus sorbitol plus D-glucose)(aq) and two of the subsystems at the temperature 298.15 K [J].
Hu, YF ;
Wang, ZC .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1997, 29 (08) :879-884
[7]   The linear isopiestic relations for the saturated system (B-C-D-A2(sat)-A1) whose subsystem (B-C-D-A1) conforms to the Zdanovskii rule and the Stokes-Robinson relation [J].
Hu, YF ;
Wang, ZC .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1998, 94 (21) :3251-3254
[8]   ISOPIESTIC STUDIES ON (NACL(M(B))+NH4CL(M(C))+BACL2(M(D)))(AQ) AT THE TEMPERATURE 298.15-K - A QUATERNARY SYSTEM OBEYING ZDANOVSKII RULE [J].
HU, YF ;
WANG, ZC .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (04) :429-433
[9]   Solubility of mannitol in aqueous sodium chloride by the isopiestic method [J].
Hu, YF .
JOURNAL OF SOLUTION CHEMISTRY, 1998, 27 (03) :255-260
[10]   THERMODYNAMICS OF TERNARY SYSTEM MANNITOL-SODIUM CHLORIDE-WATER AT 25 DEGREES FROM SOLUBILITY AND VAPOR PRESSURE MEASUREMENTS [J].
KELLY, FJ ;
STOKES, RH ;
ROBINSON, RA .
JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (11) :1958-&