High temperature oxidation behavior of Cr-Mn-Fe-Co-Ni high entropy alloy

被引：162

作者：

Kim, Young-Kyun ^{[1
]}

Joo, Yeun-Ah ^{[1
]}

Kim, Hyoung Seop ^{[2
]}

Lee, Kee-Ahn ^{[1
]}

机构：

[1] Inha Univ, Dept Mat Sci & Engn, Incheon 22212, South Korea

[2] POSTECH, Dept Mat Sci & Engn, Pohang 37673, South Korea

来源：

INTERMETALLICS | 2018年 / 98卷

关键词：

High entropy alloy; High temperature oxidation; Single solid solution phase; Microstructure; Oxidation behavior; PHASE-FORMATION; CRMNFECONI; MICROSTRUCTURE; STRESS;

D O I：

10.1016/j.intermet.2018.04.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study examined the surface oxidation properties of Cr-Mn-Fe-Co-Ni high entropy alloy (HEA) at high temperatures (900 degrees C, 1000 degrees C, 1100 degrees C/24 h) in the 21%O-2 and 79%N-2 atmosphere. An initial observation of microstructures confirmed that they consisted of random FCC solid solution, and the average grain size was measured at 245.5 pm. High-temperature oxidation tests of the Cr-Mn-Fe-Co-Ni HEA showed that its weight gained by 1.76, 4.45, and 9.08 mg/cm(2) at 900 degrees C, 1000 degrees C, and 1100 degrees C, respectively, and all three temperature conditions represented typical parabolic curves. Observation of its surface found that Cr2O3 and Mn2O3 were main oxides on a specimen tested at 900 degrees C, while (Mn, Cr)(3)O-4 and Mn3O4 were mostly shown to be main oxides on a specimen tested at 1000 degrees C and 1100 degrees C, despite the presence of Cr2O3. The high-temperature oxidation behavior of Cr-Mn-Fe-Co-Ni HEAs was found to have been largely affected by Cr and Mn elements. The resultant kirkendall pore generation, change in the concentration of elements, internal oxidation and Mn2O3-o Mn3O4 transformation were found to affect the oxidation resistance of Cr-Mn-Fe-Co-Ni high entropy alloy.

引用

页码：45 / 53

页数：9

共 28 条

[21] Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements [J].

Tong, CJ ;

Chen, MR ;

Chen, SK ;

Yeh, JW ;

Shun, TT ;

Lin, SJ ;

Chang, SY .

METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2005, 36A (05) :1263-1271

[22] Sluggish diffusion in Co-Cr-Fe-Mn-Ni high-entropy alloys [J].

Tsai, K. -Y. ;

Tsai, M. -H. ;

Yeh, J. -W. .

ACTA MATERIALIA, 2013, 61 (13) :4887-4897

[23] Physical Properties of High Entropy Alloys [J].

Tsai, Ming-Hung .

ENTROPY, 2013, 15 (12) :5338-5345

[24] Effect of aging temperature on microstructure and properties of AlCoCrCuFeNi high-entropy alloy [J].

Wen, L. H. ;

Kou, H. C. ;

Li, J. S. ;

Chang, H. ;

Xue, X. Y. ;

Zhou, L. .

INTERMETALLICS, 2009, 17 (04) :266-269

[25] Alloy Design Strategies and Future Trends in High-Entropy Alloys [J].

Yeh, Jien-Wei .

JOM, 2013, 65 (12) :1759-1771

[26] Guidelines in predicting phase formation of high-entropy alloys [J].

Zhang, Y. ;

Lu, Z. P. ;

Ma, S. G. ;

Liaw, P. K. ;

Tang, Z. ;

Cheng, Y. Q. ;

Gao, M. C. .

MRS COMMUNICATIONS, 2014, 4 (02) :57-62

[27] Solid-solution phase formation rules for multi-component alloys [J].

Zhang, Yong ;

Zhou, Yun Jun ;

Lin, Jun Pin ;

Chen, Guo Liang ;

Liaw, Peter K. .

ADVANCED ENGINEERING MATERIALS, 2008, 10 (06) :534-538

[28] Synthesis and properties of multiprincipal component AlCoCrFeNiSix alloys [J].

Zhu, J. M. ;

Fu, H. M. ;

Zhang, H. F. ;

Wang, A. M. ;

Li, H. ;

Hu, Z. Q. .

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2010, 527 (27-28) :7210-7214

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