A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster

被引：11

作者：

Yuge, Hidetaka ^{[1
]}

Asahi, Shin-ichiro ^{[1
]}

Miyamoto, T. Ken ^{[1
]}

机构：

[1] Kitasato Univ, Sch Sci, Dept Chem, Kanagawa 2288555, Japan

来源：

DALTON TRANSACTIONS | 2009年 / 13期

关键词：

INTRAMOLECULAR ELECTRON-TRANSFER; SELF-ASSEMBLED MONOLAYER; REDOX PROPERTIES; LIGAND-EXCHANGE; COMPLEXES; RUTHENIUM; DIMERS; GOLD; SPECTROSCOPY; COALESCENCE;

D O I：

10.1039/b901050p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Deacetoxylation of the oxo-centered triruthenium acetate cluster by acetyl chloride or triethylsilyl chloride led to the formation of a versatile precursor [Ru3O(OAc)(5)(Cl)(4-methylpyridine)(2)(CNt-Bu)], whose chloro ligand was readily substituted by other bridging ligands, i.e. alkoxides, carboxylates or sulfides.

引用

页码：2287 / 2289

页数：3