9-isothiocyanatoanthracene as a versatile starting compound in the chemistry of anthracen-9-yl derivatives

被引：11

作者：

Janovec, L

Suchár, G

Imrich, J

Kristian, P ^{[1
]}

Sasinková, V

Alföldi, J

Sedlák, E

机构：

[1] Safarik Univ, Dept Organ Chem, SK-04167 Kosice, Slovakia

[2] Slovak Acad Sci, Inst Chem, SK-84238 Bratislava, Slovakia

[3] Safarik Univ, Fac Sci, Dept Biochem, SK-04167 Kosice, Slovakia

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2002年 / 67卷 / 05期

关键词：

isothiocyanates; thioureas; 9-isothiocyanatoanthracene; anthracenylthioureas; kinetics; IR spectroscopy; C-13 NMR spectroscopy; fluorescence;

D O I：

10.1135/cccc20020665

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis, structure and reactivity of 9-isothiocyanatoanthracene (5) likewise the conformation of the corresponding thioureas (6a-6i) have been studied. The C-13 NMR substituent chemical shift values of the NCS group and correlations between spectral parameters (IR, NMR) and rate constans of reactions of 5, acridin-9-yl (14), phenyl (15) and benzoyl isothiocyanate (16) with butylamine were found. Significant increase of the fluorescence of the synthesized anthracenylthioureas with amino acid rests refers to the possibility to use 5 as potential biomarker.

引用

页码：665 / 678

页数：14

共 33 条

[1] C-13 NMR-SPECTRA AND SUBSTITUENT EFFECTS OF META-SUBSTITUTED AND PARA-SUBSTITUTED BENZOYL ISOTHIOCYANATES [J].