Homopolymerization and Copolymerization with Styrene of Various Alkoxyvinylsilanes and Oxidative Transformation of C-Si Bond in the Resulting Copolymers to Afford Poly[(vinyl alcohol)-co-styrene]s

被引：7
作者：
Ihara, Eiji [1 ]
Kurokawa, Atsushi [1 ]
Itoh, Tomomichi [1 ]
Inoue, Kenzo [1 ]
机构：
[1] Ehime Univ, Venture Business Lab, Grad Sch Sci & Engn, Dept Mat Sci & Biotechnol, Matsuyama, Ehime 7908577, Japan
来源：
POLYMER JOURNAL | 2008年 / 40卷 / 12期
关键词：
Radical Polymerization; Copolymerization; Poly(alkoxyvinylsilane); Polystyrene; Polymer Reaction;
D O I：
10.1295/polymj.PJ2008113
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Radical (co)polymerization behavior of alkoxyvinylsdanes [tri(isobutoxy)vinylsilane 1, triethoxyvinylsilane 2, di(isobutoxy)-methylvinyisilane 3, di(isobutoxy)phenylvinyl si lane 4, diethoxymethylvinylsilane 5, and diethoxyphenylvinylsilane 6] was systematically investigated. Homopolymerization and copolymerization with styrene of these alkoxyvinylsilanes were performed under various conditions in order to find appropriate initiating systems for the radical polymerizations. Transformation of some of the copolymers into poly[(vinyl alcohol)-co-styrene]s was examined via oxidative cleavage of the Si-C bonds in the alkoxyvinylsilane repeating units.
引用
收藏
页码：1140 / 1148
页数：9
相关论文
共 23 条
  • [1] ANDRIANOV KA, 1977, VYSOKOMOL SOEDIN A+, V19, P749
  • [2] [Anonymous], 1957, US Patent, Patent No. 2777869
  • [3] CO-POLYMERIZATION OF STYRENE AND ACRYLONITRILE WITH FUNCTIONAL SILANES
    BAJAJ, P
    GUPTA, DC
    [J]. EUROPEAN POLYMER JOURNAL, 1979, 15 (03) : 271 - 275
  • [4] Thermal and oxidative degradation of vinyl triethoxy silane -: methyl methacrylate copolymers
    Çaykara, T
    Eroglu, MS
    Güven, O
    [J]. POLYMER DEGRADATION AND STABILITY, 1999, 63 (01) : 65 - 70
  • [5] DIXON KW, 1999, POLYM HDB, V1, P1
  • [6] Anionic synthesis of narrow molecular weight distribution poly(trimethylvinylsilane) (PTMVS), polystyrene-PTMVS block copolymers, and poly(phenyldimethylvinylsilane). Conversion of poly(phenyldimethylvinylsilane) into poly(fluorodimethylvinylsilane)
    Gan, YD
    Prakash, S
    Olah, GA
    Weber, WP
    HogenEsch, TE
    [J]. MACROMOLECULES, 1996, 29 (26) : 8285 - 8288
  • [7] Synthesis of N-vinylpyrrolidone-vinyltrimethoxysilane copolymers
    Gorbunova, MN
    Surkov, VD
    Fedoseev, MS
    [J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2001, 74 (09) : 1608 - 1609
  • [8] Preparation and properties of organic-inorganic hybrid gel films based on polyvinylpolysilsesquioxane synthesized from trimethoxy(vinyl)silane
    Gunji, T
    Okonogi, H
    Sakan, T
    Takamura, N
    Arimitsu, K
    Abe, Y
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (08) : 580 - 588
  • [9] A novel synthetic strategy for copolymers of vinyl alcohol:: Radical copolymerization of alkoxyvinylsilanes with styrene and oxidative transformation of C-Si(OR)2Me into C-OH in the copolymers to afford poly(vinyl alcohol-ran-styrene)s
    Ihara, Eiji
    Kurokawa, Atsushi
    Itoh, Tomomichi
    Inoue, Kenzo
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (16) : 3648 - 3658
  • [10] KEOGH MJ, 1985, Patent No. 4526930
123