The Zintl ion [Pb10]2-:: A rare example of a homoatomic closo cluster

被引：80

作者：

Spiekermann, Annette ^{[1
]}

Hoffinann, Stephan D. ^{[1
]}

Fassler, Thomas F. ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 21期

关键词：

cluster compounds; cryptands; lead; Wade's rules; Zintl anions;

D O I：

10.1002/anie.200503916

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Closed encounters: A closed deltahedral homoatomic cluster, [Pb10]2-, is structurally characterized. When this "empty" cluster is considered together with the recently published filled cluster [Ni@Pb10]2-, a striking parallel to the fullerenes emerges: Zintl ions form polyhedral cages that can enclose a central atom without any major structural alterations. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3459 / 3462

页数：4

共 40 条

[1] METAL-METAL INTERACTIONS IN CHAIN COMPOUNDS OF GOLD(I) - SYNTHESES AND CRYSTAL-STRUCTURES OF CHLOROTETRAHYDROTHIOPHENEGOLD(I), BROMOTETRAHYDROTHIOPHENEGOLD(I) AND IODOTETRAHYDROSELENOPHENEGOLD(I) [J].

AHRLAND, S ;

DREISCH, K ;

NOREN, B ;

OSKARSSON, A .

MATERIALS CHEMISTRY AND PHYSICS, 1993, 35 (3-4) :281-289

[2]

BELIN C, 1991, NEW J CHEM, V15, P931

[3] HOMOPOLYATOMIC ANIONS AND CONFIGURATIONAL QUESTIONS - SYNTHESIS AND STRUCTURE OF NONAGERMANIDE(2-) IONS AND NONAGERMANIDE(4-) IONS, GE92- AND GE94-1 [J].

BELIN, CHE ;

CORBETT, JD ;

CISAR, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (22) :7163-7169

[4] Syntheses, crystal structures, and density functional theory calculations of the closo-[1-M(CO)3(η4-E9)]4- (E = Sn, Pb; M = Mo, W) cluster anions and solution NMR spectroscopic characterization of [1-M(CO)3(η4-Sn9)]4-(M = Cr, Mo, W) [J].

Campbell, J ;

Mercier, HPA ;

Franke, H ;

Santry, DP ;

Dixon, DA ;

Schrobilgen, GJ .

INORGANIC CHEMISTRY, 2002, 41 (01) :86-107

[5] The closo-Ge-5(2-) anion: Synthesis, crystal structure, and Raman spectrum of (2,2,2-crypt-K+)(2)Ge-5(2-)center dot THF [J].

Campbell, J ;

Schrobilgen, GJ .

INORGANIC CHEMISTRY, 1997, 36 (18) :4078-4081

[6]

Chitsaz S, 2000, Z ANORG ALLG CHEM, V626, P775, DOI 10.1002/(SICI)1521-3749(200003)626:3<775::AID-ZAAC775>3.0.CO

[7]

2-H

[8] Diverse naked clusters of the heavy main-group elements. Electronic regularities and analogies [J].

Corbett, JD .

STRUCTURAL AND ELECTRONIC PARADIGMS IN CLUSTER CHEMISTRY, 1997, 87 :157-193

[9] STABLE HOMOPOLYATOMIC ANIONS - SYNTHESIS AND CRYSTAL-STRUCTURES OF SALTS CONTAINING PENTAPLUMBIDE(2-) AND PENTASTANNIDE(2-) ANIONS [J].

EDWARDS, PA ;

CORBETT, JD .

INORGANIC CHEMISTRY, 1977, 16 (04) :903-907

[10] CLOSO-[CRPB9(CO)3]4- - A 100 YEAR HISTORY OF THE NONAPLUMBIDE TETRA-ANION [J].

EICHHORN, BW ;

HAUSHALTER, RC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (13) :937-938

← 1 2 3 4 →