Identifying the high activity of the basal plane in 1T-phase MoS2 towards electrochemical hydrogen evolution

被引:9
作者
Shi, Yanmei
Zhang, Bin [1 ]
机构
[1] Tianjin Univ, Dept Chem, Sch Sci, Tianjin 300072, Peoples R China
关键词
TRANSITION-METAL-DICHALCOGENIDE; NANOSHEETS; CATALYSIS;
D O I
10.1039/c8qi00317c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
As a promising alternative hydrogen evolution catalyst, MoS2 is well known for its active edge sites and the inert basal plane. Now, 1T-MoS2 crystals are prepared and processed into different electrochemical microcells based on individual MoS2 nanosheets to reveal that the basal plane of 1T-MoS2 is highly catalytically active.
引用
收藏
页码:1490 / 1492
页数:3
相关论文
共 14 条
[1]   Understanding catalysis in a multiphasic two-dimensional transition metal dichalcogenide [J].
Chou, Stanley S. ;
Sai, Na ;
Lu, Ping ;
Coker, Eric N. ;
Liu, Sheng ;
Artyushkova, Kateryna ;
Luk, Ting S. ;
Kaehr, Bryan ;
Brinker, C. Jeffrey .
NATURE COMMUNICATIONS, 2015, 6
[2]   Biornimetic hydrogen evolution:: MoS2 nanoparticles as catalyst for hydrogen evolution [J].
Hinnemann, B ;
Moses, PG ;
Bonde, J ;
Jorgensen, KP ;
Nielsen, JH ;
Horch, S ;
Chorkendorff, I ;
Norskov, JK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (15) :5308-5309
[3]   Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts [J].
Jaramillo, Thomas F. ;
Jorgensen, Kristina P. ;
Bonde, Jacob ;
Nielsen, Jane H. ;
Horch, Sebastian ;
Chorkendorff, Ib .
SCIENCE, 2007, 317 (5834) :100-102
[4]   Synthesis of MoS2 and MoSe2 Films with Vertically Aligned Layers [J].
Kong, Desheng ;
Wang, Haotian ;
Cha, Judy J. ;
Pasta, Mauro ;
Koski, Kristie J. ;
Yao, Jie ;
Cui, Yi .
NANO LETTERS, 2013, 13 (03) :1341-1347
[5]  
Li H, 2016, NAT MATER, V15, P48, DOI [10.1038/NMAT4465, 10.1038/nmat4465]
[6]   MoS2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction [J].
Li, Yanguang ;
Wang, Hailiang ;
Xie, Liming ;
Liang, Yongye ;
Hong, Guosong ;
Dai, Hongjie .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (19) :7296-7299
[7]   Gram-Scale Aqueous Synthesis of Stable Few-Layered 1T-MoS2: Applications for Visible-Light-Driven Photocatalytic Hydrogen Evolution [J].
Liu, Qin ;
Li, Xiuling ;
He, Qun ;
Khalil, Adnan ;
Liu, Daobin ;
Xiang, Ting ;
Wu, Xiaojun ;
Song, Li .
SMALL, 2015, 11 (41) :5556-5564
[8]   Stable Metallic 1T-WS2 Nanoribbons Intercalated with Ammonia Ions: The Correlation between Structure and Electrical/Optical Properties [J].
Liu, Qin ;
Li, Xiuling ;
Xiao, Zhangru ;
Zhou, Yu ;
Chen, Haipin ;
Khalil, Adnan ;
Xiang, Ting ;
Xu, Junqing ;
Chu, Wangsheng ;
Wu, Xiaojun ;
Yang, Jinlong ;
Wang, Chengming ;
Xiong, Yujie ;
Jin, Chuanhong ;
Ajayan, Pulickel M. ;
Song, Li .
ADVANCED MATERIALS, 2015, 27 (33) :4837-4844
[9]   2D Transition-Metal-Dichalcogenide-Nanosheet-Based Composites for Photocatalytic and Electrocatalytic Hydrogen Evolution Reactions [J].
Lu, Qipeng ;
Yu, Yifu ;
Ma, Qinglang ;
Chen, Bo ;
Zhang, Hua .
ADVANCED MATERIALS, 2016, 28 (10) :1917-1933
[10]   Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS2 Nanosheets [J].
Lukowski, Mark A. ;
Daniel, Andrew S. ;
Meng, Fei ;
Forticaux, Audrey ;
Li, Linsen ;
Jin, Song .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (28) :10274-10277