Synthesis of Novel Diselenide-Linked Porphyrin Dimers under Phase-Transfer Catalysis Condition and Their Interactions with DNA

被引：6

作者：

Xue, Zhi ^{[1
]}

Kwong, Daniel Wei-Jing ^{[2
]}

Xue, Ling-Wei ^{[3
]}

Liu, Qing ^{[1
]}

Hou, An-Xin ^{[1
]}

Wong, Wai-Kwok ^{[1
,2
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China

[3] Pingdingshan Univ, Coll Chem & Chem Engn, Pingdingshan 467002, Peoples R China

来源：

CHEMISTRY & BIODIVERSITY | 2009年 / 6卷 / 07期

关键词：

DIPHENYL DISELENIDE; CATIONIC PORPHYRINS; CANCER PREVENTION; SELENIUM; ANTIBACTERIAL; PHOTOCLEAVAGE; COMBINATION; COMPLEXES; MECHANISM; POSITION;

D O I：

10.1002/cbdv.200800182

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Novel diselenide-linked porphyrin dimers were synthesized under phase-transfer catalysis conditions. The targeted compounds were characterized by H-1-NMR, high-resolution mass spectrometry, UV/VIS and fluorescence spectroscopies, redox-potential measurements, and elemental analysis. The interaction of the title compounds with DNA was studied using UV/VIS, fluorescence, and circular dichroism (CD) spectroscopies. The relative rates of singlet-oxygen production from the diselenide-linked porphyrin dimers upon photoirradiation were also measured.

引用

页码：1131 / 1143

页数：13

共 6 条

[1] Rapid and Convenient Thioester Synthesis Under Phase-Transfer Catalysis Conditions
Simion, Cristian
Hashimoto, Iwao
Mitoma, Yoshiharu
Simion, Alina Marieta
Egashira, Naoyoshi
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (12) : 2480 - 2488
[2] A novel synthesis of selenides and selenol esters using liquid-liquid phase-transfer catalysis
Takido, T
Toriyama, M
Yamashita, K
Suwa, T
Seno, M
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2003, 178 (02) : 319 - 326
[3] Efficient synthesis of functional long-chain alkyl disulfides under liquid-liquid phase-transfer catalysis: The analysis of chemical equilibrium and phase-transfer mechanism
Li, Dongxiang
Li, Jihong
Zhang, Zhupeng
Yan, Lei
Liu, Na
Li, Chunfang
Hou, Wanguo
CATALYSIS COMMUNICATIONS, 2017, 89 : 9 - 13
[4] Regioselective Synthesis of Novel Functionalized Dihydro-1,4-thiaselenin-2-ylsufanyl Derivatives under Phase Transfer Catalysis
Filippov, Andrey S.
Amosova, Svetlana, V
Albanov, Alexander, I
Potapov, Vladimir A.
CATALYSTS, 2022, 12 (08)
[5] Efficient Regioselective Synthesis of Novel Ensembles of Organylselanyl-Functionalized Divinyl Sulfides and 1,3-Thiaselenoles under Phase Transfer Catalysis Conditions
Filippov, Andrey S.
Amosova, Svetlana V.
Makhaeva, Nataliya A.
Albanov, Alexander I.
Potapov, Vladimir A.
CATALYSTS, 2023, 13 (08)
[6] Regio- and stereoselective synthesis of (Z)-(2,3-dihydro-1,4-thiaselenin-2-yl) vinyl sulfides from 2-bromomethyl-1,3-thiaselenole under phase-transfer catalysis conditions
Filippov, Andrey S.
Amosova, Svetlana V.
Potapov, Vladimir A.
CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2020, 56 (09) : 1237 - 1240

← 1 →