Fluorimetric determination of aluminium using sequential injection analysis (SIA): State of our art and future developments

被引:23
作者
Al-Kindy, Salma M. Z.
Suliman, Fakhr Eldin O.
Pillay, Avin E.
机构
[1] Sultan Qaboos Univ, Coll Sci, Dept Chem, Al Khoud 123, Oman
[2] Petr Inst, Abu Dhabi, U Arab Emirates
关键词
aluminium; fluorimetric determination; sequential injection analysis;
D O I
10.1080/10739140600963830
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper describes some of our recent advances and proposed future work in the area of fluorimetric determination of Al using sequential injection analysis (SIA). A rapid, automated system was developed with turnover times for sample analysis of < 2 min, and attainable limits of detection of < 1 ng/mL. The method is cost-effective and highly competitive. It utilizes three different approaches: (i) molecular imprinted polymers (MIPs); (ii) micellar enhanced treatment; and (iii) renewable surface application. The merits and limitations of each approach are discussed, and the optimum conditions of analysis are presented. The overall sensitivity achieved was more than adequate for general analysis. Proposed new developments involve greater signal enhancement, and improved analytical strategy. The facility is capable of routine application, and is highly beneficial to developing countries in need of cost-effective techniques for analysis of environmental samples, body fluids, and foodstuffs.
引用
收藏
页码:619 / 633
页数:15
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