High precision measurement of iron isotopes by plasma source mass spectrometry

被引：156
|
作者：
Belshaw, NS [1 ]
Zhu, XK [1 ]
Guo, Y [1 ]
O'Nions, RK [1 ]
机构：
[1] Univ Oxford, Dept Earth Sci, Oxford OX1 3PR, England
来源：
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2000年 / 197卷
关键词：
plasma source mass spectrometry; Fe-isotopes; stable isotope;
D O I：
10.1016/S1387-3806(99)00245-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Multiple-collector inductively coupled plasma mass spectrometry has been used for the precise measurement of natural variations in the isotopic composition of Fe. The contributions of Ar-O and Ar-N molecular species to the mass spectrum in the Fe mass region are minimised and the repeatability of the Fe-57/Fe-54 ratio of a sample Fe solution relative to the IRMM-14 Fe isotope standard is better than 100 ppm at 95% confidence. Variations in sample Fe-57/Fe-54 ratio are expressed as epsilon(57)Fe units, which are deviations in parts per 10(4) from the same ratio in the IRMM-14 Fe isotope reference standard. Measurements of epsilon(57)Fe are presented for samples of meteoritic iron and terrestrial Fe-oxides and carbonates. (C) 2000 Elsevier Science B.V.
引用
收藏
页码：191 / 195
页数：5
相关论文
共 50 条
  • [1] High precision measurement of titanium isotope ratios by plasma source mass spectrometry
    Zhu, XK
    Makishima, A
    Guo, Y
    Belshaw, NS
    O'Nions, RK
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2002, 220 (01) : 21 - 29
  • [2] Precise measurement of Fe isotopes in marine samples by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS)
    de Jong, Jeroen
    Schoemann, Veronique
    Tison, Jean-Louis
    Becquevort, Sylvie
    Masson, Florence
    Lannuzel, Delphine
    Petit, Jerome
    Chou, Lei
    Weis, Dominique
    Mattielli, Nadine
    ANALYTICA CHIMICA ACTA, 2007, 589 (01) : 105 - 119
  • [3] MEASUREMENT OF MERCURY METHYLATION IN SEDIMENTS BY USING ENRICHED STABLE MERCURY ISOTOPES COMBINED WITH METHYLMERCURY DETERMINATION BY GAS-CHROMATOGRAPHY INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY
    HINTELMANN, H
    EVANS, RD
    VILLENEUVE, JY
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1995, 10 (09) : 619 - 624
  • [4] Iron Isotopic Measurement using Large-Geometry High-Resolution Multi-Collector Inductively Coupled Plasma Mass Spectrometer
    Lei, Yvtian
    Li, Ming
    Wang, Zaicong
    Zhu, Yangtao
    Hu, Zhaochu
    Li, Yongsheng
    Chai, Xinna
    ATOMIC SPECTROSCOPY, 2022, 43 (03) : 214 - 222
  • [5] Determination of natural Cu-isotope variation by plasma-source mass spectrometry: implications for use as geochemical tracers
    Zhu, XK
    O'Nions, RK
    Guo, Y
    Belshaw, NS
    Rickard, D
    CHEMICAL GEOLOGY, 2000, 163 (1-4) : 139 - 149
  • [6] Development of photosynthesis and respiration measurement system using mass spectrometry
    Goto, E
    Takakura, T
    Okamura, N
    Nishi, I
    Futami, J
    INTERNATIONAL SYMPOSIUM ON PLANT PRODUCTION IN CLOSED ECOSYSTEMS - AUTOMATION, CULTURE, AND ENVIRONMENT, 1997, (440): : 464 - 468
  • [7] Quantitative imaging of subcellular metabolism with stable isotopes and multi-isotope imaging mass spectrometry
    Steinhauser, Matthew L.
    Lechene, Claude P.
    SEMINARS IN CELL & DEVELOPMENTAL BIOLOGY, 2013, 24 (8-9) : 661 - 667
  • [8] TOWARDS THE NEXT GENERATION OF PLASMA SOURCE-MASS SPECTROMETERS
    HIEFTJE, GM
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1992, 7 (06) : 783 - 790
  • [9] Fundamental aspects of ion extraction in inductively coupled plasma mass spectrometry
    Niu, H
    Houk, RS
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1996, 51 (08) : 779 - 815
  • [10] High-precision Cu isotopic analysis of human dietary Cu sources via multi-collector ICP-mass spectrometry
    Sullivan, Kaj, V
    Moser, Katharina
    Costas-Rodriguez, Marta
    Bolea-Fernandez, Eduardo
    Vanhaecke, Frank
    FOOD CHEMISTRY, 2025, 470
12345