Sensitive on-chip methane detection with a cryptophane-A cladded Mach-Zehnder interferometer

被引:51
作者
Dullo, Firehun Tsige [1 ,2 ]
Lindecrantz, Susan [1 ]
Jagerska, Jana [1 ]
Hansen, Jorn H. [3 ]
Engqvist, Magnus [3 ]
Solbo, Stian Andre [2 ]
Helleso, Olav Gaute [1 ]
机构
[1] UiT Arctic Univ Norway, Dept Phys & Technol, N-9037 Tromso, Norway
[2] Northern Res Inst, N-9294 Tromso, Norway
[3] UiT Arctic Univ Norway, Dept Chem, N-9037 Tromso, Norway
关键词
SENSOR;
D O I
10.1364/OE.23.031564
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We report a methane sensor based on an integrated Mach-Zehnder interferometer, which is cladded by a styrene-acrylonitrile film incorporating cryptophane-A. Cryptophane-A is a supramolecular compound able to selectively trap methane, and its presence in the cladding leads to a 17-fold sensitivity enhancement. Our approach, based on 3 cm-long low-loss Si3N4 rib waveguides, results in a detection limit as low as 17 ppm. This is 1-2 orders of magnitude lower than typically achieved with chip-scale low-cost sensors. (C) 2015 Optical Society of America
引用
收藏
页码:31564 / 31573
页数:10
相关论文
共 26 条
[1]   Silane Layers on Silicon Surfaces: Mechanism of Interaction, Stability, and Influence on Protein Adsorption [J].
Aissaoui, Nesrine ;
Bergaoui, Latifa ;
Landoulsi, Jessem ;
Lambert, Jean-Francois ;
Boujday, Souhir .
LANGMUIR, 2012, 28 (01) :656-665
[2]  
[Anonymous], 1980, ANAL CHEM, V52, P2242
[3]  
[Anonymous], 2013, CLIM CHANG 2013 PHYS
[4]   Study of a new evanescent wave optical fibre sensor for methane detection based on cryptophane molecules [J].
Benounis, M ;
Jaffrezic-Renault, N ;
Dutasta, JP ;
Cherif, K ;
Abdelghani, A .
SENSORS AND ACTUATORS B-CHEMICAL, 2005, 107 (01) :32-39
[5]   A novel, low-cost, high performance dissolved methane sensor for aqueous environments [J].
Boulart, Cedric ;
Mowlem, Matthew C. ;
Connelly, Douglas P. ;
Dutasta, Jean-Pierre ;
German, Christopher R. .
OPTICS EXPRESS, 2008, 16 (17) :12607-12617
[6]   Cryptophanes and Their Complexes-Present and Future [J].
Brotin, Thierry ;
Dutasta, Jean-Pierre .
CHEMICAL REVIEWS, 2009, 109 (01) :88-130
[7]   2-STEP SYNTHESIS OF D3 AND C3H CRYPTOPHANES [J].
CANCEILL, J ;
COLLET, A .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (09) :582-584
[8]   Encapsulation of Small Gas Molecules by Cryptophane-111 in Organic Solution. 1. Size- and Shape-Selective Complexation of Simple Hydrocarbons [J].
Chaffee, Kathleen E. ;
Fogarty, Heather A. ;
Brotin, Thierry ;
Goodson, Boyd M. ;
Dutasta, Jean-Pierre .
JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (49) :13675-13684
[9]  
Densmore A., 2008, Advances in Optical Technologies, V2008, DOI 10.1155/2008/725967
[10]   Single-Mode Limit and Bending Losses for Shallow Rib Si3N4 Waveguides [J].
Dullo, Firehun Tsige ;
Tinguely, Jean-Claude ;
Solbo, Stian Andre ;
Helleso, Olav Gaute .
IEEE PHOTONICS JOURNAL, 2015, 7 (01)