Facile fabrication and electrochemical properties of high-quality reduced graphene oxide/cobalt sulfide composite as anode material for lithium-ion batteries

被引:57
作者
Li, Zhangpeng [1 ]
Li, Wenyue [1 ,2 ]
Xue, Hongtao [1 ]
Kang, Wenpei [1 ]
Yang, Xia [1 ]
Sun, Mingliang [1 ]
Tang, Yongbing [1 ,2 ]
Lee, Chun-Sing [1 ]
机构
[1] City Univ Hong Kong, COSDAF, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China
[2] Chinese Acad Sci, Shenzhen Inst Adv Technol, Funct Thin Films Res Ctr, Shenzhen, Peoples R China
关键词
PHASE-CONTROLLED SYNTHESIS; ELECTRODE MATERIALS; PERFORMANCE; COBALT; SHEETS; NANOPARTICLES; NANOSHEETS; CAPACITY; MICROSPHERES; NANOSPHERES;
D O I
10.1039/c4ra06067a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A reduced graphene oxide (rGO)/cobalt sulfide composite is synthesized with a simple and efficient ultrasound-assisted wet chemical method. The morphology and microstructure of the composite are examined with field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectroscopy. The results confirm that cobalt sulfide nanoparticles are homogeneously and tightly attached on the surfaces of rGO. As an anode material for lithium-ion batteries, this composite delivers a high reversible capacity of 994 mA h g(-1) after 150 cycles at a current density of 200 mA g(-1). A synergistic effect combining the merits of rGO and cobalt sulfide nanoparticles endows the composite with superior electrochemical performances over those of pure cobalt sulfide.
引用
收藏
页码:37180 / 37186
页数:7
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