[(1RS,7RS,8RS,14RS)-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene-κ4N1,4,8,11]nickel(II) perchlorate

被引：6

作者：

Curtis, NF ^{[1
]}

Weatherburn, DC ^{[1
]}

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington, New Zealand

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷

关键词：

D O I：

10.1107/S1600536802012205

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ni(C24H32N4)](ClO4), has singlet ground-state nickel(II) complex cations with tetrahedrally twisted [+/-0.013 (4) Angstrom] square-planar coordination by four N atoms of the 14-membered diamine-diimine tetraaza-macrocycle and perchlorate anions. A perchlorate O atom is sited near the tetragonal axis [Ni...O 2.694 (4) Angstrom], with both N-H groups oriented towards the other side of the plane forming N-H...O hydrogen bonds to O atoms of different perchlorate ions, with no O atom near the nickel(II) tetragonal axis.

引用

页码：m423 / m425

页数：3

共 15 条

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