One-pot synthesis of bis-1,5,3-dithiazepanes and their sorption properties toward silver(I) and palladium(II)

被引：8

作者：

Akhmetova, V. R. ^{[1
]}

Anpilogova, G. R. ^{[2
]}

Khabibullina, G. R. ^{[1
]}

Akhmadiev, N. S. ^{[1
]}

Ibragimov, A. G. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia

[2] Russian Acad Sci, Inst Organ Chem, Ufa Sci Ctr, Ufa 450054, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2014年 / 87卷 / 05期

关键词：

Palladium; Sorption Capacity; Sorbate; Sorption Property; Hydrochloric Acid Solution;

D O I：

10.1134/S1070427214050085

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The possibility of one-pot synthesis of bis-1,5,3-dithiazepanes by multicomponent condensation of amines (NH4Cl, hydrazine, and 1,2-ethylenediamine) with formaldehyde and 1,2-ethanedithiol was described. Their sorption properties relative to Ag(I) and Pd(II) were studied by a static method. It was shown that at room temperature bis-1,5,3-dithiazepanes recovered with high efficiency silver(I) and palladium(II) from nitrate solutions and hydrochloric acid solutions, respectively.

引用

页码：585 / 590

页数：6

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