High performance of Pt/TiO2-nanotubes/Ti mesh electrode and its application in flexible dye-sensitized solar cell

被引:16
作者
Bao, Zhongqiu [1 ]
Xie, Haixian [1 ]
Rao, Jun [1 ]
Chen, Lei [1 ]
Wei, Yun [1 ]
Li, Haifeng [1 ]
Zhou, Xingfu [1 ]
机构
[1] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Ti mesh; Solar energy materials; Electron microscopy; Stuctural; NANOTUBE ARRAYS; TI SUBSTRATE; EFFICIENCY;
D O I
10.1016/j.matlet.2014.03.041
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A platinum (Pt) nanoparticle-covered titania (TiO2) nanotube arrays titanium (Ti) mesh electrode (Pt/TiO2-NTs/Ti) has been successfully fabricated on Ti mesh via a thermal reduction technique by spraying H2PtCl6 center dot 6H(2)O isopropanol solution onto vertically oriented TiO2 nanotube arrays. Electrochemical impedance spectroscopy (EIS) and cyclic voltammerty (CV) investigations showed that the Pt/TiO2-NTs/Ti mesh electrode has superior electrocatalytic activity, good stability, and low ohmic series resistance (3.41 Omega cm(2)). With the diamond-shaped holes, the actual area of the Ti mesh electrode was less than that of the Pt/FTO glass electrode, but the catalytic activities were essentially equal. A flexible dye-sensitized solar cell was assembled from the Pt/TiO2-NTs/Ti mesh electrode and a sensitized TiO2 photoanode on Ti foil substrate, and it reached a power conversion efficiency (PCE) of 5.6% using a backside illumination simulated solar light (AM 1.5G, 100 mW cm(-2)). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:158 / 160
页数:3
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