Potassium fluoride/basic alumina as far superior heterogeneous catalyst for the chemoselective conjugate addition of nitroalkanes to electron-poor alkenes having two electron-withdrawing groups in α- and β-positions

被引：20

作者：

Ballini, Roberto ^{[1
]}

Palmieri, Alessandro ^{[1
]}

机构：

[1] Univ Camerino, Green Chem Grp, Dipartimento Sci Chim, I-62032 Camerino, Italy

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2006年 / 348卷 / 10-11期

关键词：

conjugate addition; heterogeneous catalysis; nitroalkanes; potassium fluoride/basic alumina; solventless reaction;

D O I：

10.1002/adsc.200606105

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The chemoselective, conjugate addition of nitroalkanes to electron-poor alkenes, with two electron-withdrawing groups in the alpha- and beta-positions, can be easily performed at room temperature under solventless conditions using potassium fluoride/basic alumina as heterogeneous catalyst.

引用

收藏

页码：1154 / 1156

页数：3

相关论文

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