Effect of nanoparticle surface functionality on microdomain orientation in block copolymer thin films under electric field

被引：29

作者：

Bae, Joonwon ^{[1
]}

Cha, Sang-Ho ^{[2
]}

机构：

[1] Dongduk Womens Univ, Dept Appl Chem, Seoul 136714, South Korea

[2] Kyonggi Univ, Dept Chem Engn, Suwon 443760, South Korea

来源：

POLYMER | 2014年 / 55卷 / 08期

关键词：

Nanoparticle; Block copolymer; Electric field; GOLD NANOPARTICLES; DIBLOCK COPOLYMERS; MORPHOLOGICAL TRANSFORMATION; ALIGNMENT; LOCATION; SIMULATION; TEMPLATES; PARTICLES; ORDER;

D O I：

10.1016/j.polymer.2014.02.054

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The electric field induced microdomain orientations has been an interesting research topic. In this article, the effect of nanoparticle surface functionality on microdomain alignments in block copolymer/nanoparticle hybrid thin films was investigated with transmission electron microscopy experiments. The presence of gold nanoparticles influenced the microdomain orientation behaviors of block copolymer/ nanoparticle thin films. The possibility for complete alignment normal to the substrate was illustrated by controlling electric field strength, concentration, and surface ligands of nanoparticles. This work provides basic and essential data to understand the properties and behaviors of emerging block copolymer/ nanoparticle hybrid thin films. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：2014 / 2020

页数：7

共 44 条

[11] Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].

Daniel, MC ;

Astruc, D .

CHEMICAL REVIEWS, 2004, 104 (01) :293-346

[12] Directing the self-assembly of block copolymers [J].

Darling, S. B. .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (10) :1152-1204

[13] Two-dimensional confinement of nanorods in block copolymer domains [J].

Deshmukh, Ranjan D. ;

Liu, Yu ;

Composto, Russ J. .

NANO LETTERS, 2007, 7 (12) :3662-3668

[14] Divalent metal nanoparticles [J].

DeVries, Gretchen A. ;

Brunnbauer, Markus ;

Hu, Ying ;

Jackson, Alicia M. ;

Long, Brenda ;

Neltner, Brian T. ;

Uzun, Oktay ;

Wunsch, Benjamin H. ;

Stellacci, Francesco .

SCIENCE, 2007, 315 (5810) :358-361

[15] Size-dependent melting of silica-encapsulated gold nanoparticles [J].

Dick, K ;

Dhanasekaran, T ;

Zhang, ZY ;

Meisel, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (10) :2312-2317

[16] Simulation of hard particles in a phase-separating binary mixture [J].

Ginzburg, VV ;

Qiu, F ;

Paniconi, M ;

Peng, GW ;

Jasnow, D ;

Balazs, AC .

PHYSICAL REVIEW LETTERS, 1999, 82 (20) :4026-4029

[17]

Hamley I. W., 1998, The Physics of Block Copolymers

[18] Nanostructure fabrication using block copolymers [J].

Hamley, IW .

NANOTECHNOLOGY, 2003, 14 (10) :R39-R54

[19] Catalytic activity of supported au nanoparticles deposited from block copolymer micelles [J].

Jaramillo, TF ;

Baeck, SH ;

Roldan Cuenya, B ;

McFarland, EW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (24) :7148-7149

[20] Broad-wavelength-range chemically tunable block-copolymer photonic gels [J].

Kang, Youngjong ;

Walish, Joseph J. ;

Gorishnyy, Taras ;

Thomas, Edwin L. .

NATURE MATERIALS, 2007, 6 (12) :957-960

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