Carbonite, the dianion of carbon dioxide and its metal complexes

被引：22

作者：

Paparo, Albert ^{[1
]}

Okuda, Jun ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Inorgan Chem, Landoltweg 1, D-52074 Aachen, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2018年 / 869卷

关键词：

Carbonite; Carbon dioxide dianion; Dioxycarbene; Carbon dioxide activation; Tautomerism; TRIPHENYL-METHYL-SODIUM; HO-C-OH; COORDINATION CHEMISTRY; OXALATE FORMATION; ARYL ISOCYANATES; SINGLET CARBENES; INFRARED-SPECTRA; DIVALENT CARBON; FORMIC-ACID; GAS-PHASE;

D O I：

10.1016/j.jorganchem.2017.10.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chemistry freshmen learn to distinguish between nitrate NO3- and nitrite NO2- or sulfate SO42- and sulfite SO32-, but how many would know about carbonite CO22- in contrast to carbonate CO32-? This is not surprising for an anion that has never been observed in solution. However, it might be a crucial intermediate in the reductive activation of CO2. This review will track back carbonite and reflect on its relevance to carbon dioxide binding in metal complexes. (C) 2017 Published by Elsevier B.V.

引用

页码：270 / 274

页数：5

共 50 条

[1] Dinuclear metal complexes for the activation of carbon dioxide
Bheemaraju, Amarnath
Beattie, Jeffrey W.
Groysman, Stanislav
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[2] Photochemical carbon dioxide reduction with metal complexes
Fujita, E
COORDINATION CHEMISTRY REVIEWS, 1999, 185-6 : 373 - 384
[3] Carbon dioxide activation by metal complexes.
Schultz, BL
Nicholas, K
Franks, R
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U326 - U326
[4] The Interaction of Carbon Dioxide with Transition Metal Complexes
Kolomnikov, I.S.
Grigoryan, M.Kh.
1600, Editorial Board of the Journal Uspekhi Khimii (Russian Chemical Reviews) (47):
[5] Impregnation of the metal complexes into polymer plates using supercritical carbon dioxide and its application for metal plating
Zhao, X
Tabata, I
Hori, T
QUALITY TEXTILES FOR QUALITY LIFE, VOLS 1-4, 2004, : 825 - 828
[6] THE CHEMISTRY OF METAL CARBONATO AND CARBON-DIOXIDE COMPLEXES
PALMER, DA
VANELDIK, R
CHEMICAL REVIEWS, 1983, 83 (06) : 651 - 731
[7] Copolymerization of carbon dioxide and epoxides by metal coordination complexes
Kozak, Christopher M.
Ambrose, Kenson
Anderson, Timothy S.
COORDINATION CHEMISTRY REVIEWS, 2018, 376 : 565 - 587
[8] Study of Metal Complexes' Solubility in Supercritical Carbon Dioxide
Ding, Yigang
Huang, Haitao
Ding, Yao
Yang, Changyan
Ji, Jun
Wu, Yuanxin
APPLICATION OF CHEMICAL ENGINEERING, PTS 1-3, 2011, 236-238 : 411 - 416
[9] Recent developments in the activation of carbon dioxide by metal complexes
Yin, XL
Moss, JR
COORDINATION CHEMISTRY REVIEWS, 1999, 181 : 27 - 59
[10] THE ACTIVATION OF CARBON-DIOXIDE BY METAL-COMPLEXES
DARENSBOURG, DJ
KUDAROSKI, RA
ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1983, 22 : 129 - 168

← 1 2 3 4 5 →