Using magnetic coupling to implement 1H, 19F, 13C experiments in routine high resolution NMR probes

被引:5
|
作者
Bowyer, Paul [1 ,2 ]
Finnigan, Jim [1 ]
Marsden, Brian [1 ,3 ]
Taber, Bob [1 ]
Zens, Albert [1 ,4 ]
机构
[1] Agilent Technol, Santa Clara, CA 95501 USA
[2] Magritek Inc, San Diego, CA 92121 USA
[3] Washington Univ, Dept Chem, St Louis, MO 63130 USA
[4] JEOL, San Jose, CA 95116 USA
关键词
Double resonance probe; H-1-F-19; H-1; F-19; C-13;
D O I
10.1016/j.jmr.2015.10.010
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
We report in this paper the design of H-1, F-19, C-13 circuitry using magnetic coupling which can do on demand experiments where one of the three nuclei is observed and the other two are decoupled. The implementation of this circuitry in routine NMR probes is compared with capacitive coupling methods where it was found that by using magnetic coupling the performance of the routine NMR probe was not impacted by the addition of this circuitry. It is surmised that using this type of circuitry would be highly desirable for those chemists doing routine F-19 NMR. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码:190 / 198
页数:9
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