Unprecedented acetylation of phenols using a catalytic amount of magnesium powder

被引：4

作者：

Bajracharya, Gan B. ^{[1
]}

Shrestha, Suryaman Sama ^{[2
]}

机构：

[1] Nepal Acad Sci & Technol, Fac Sci, Khumaltar, Lalitpur, Nepal

[2] Tribhuvan Univ, Dept Chem, Trichandra Multiple Campus, Kathmandu, Nepal

来源：

SYNTHETIC COMMUNICATIONS | 2018年 / 48卷 / 13期

关键词：

Acetylation; free radical mechanism; magnesium; phenyl acetates; SOLVENT-FREE CONDITIONS; ACETIC-ANHYDRIDE; REUSABLE CATALYST; HIGHLY EFFICIENT; SELECTIVE ACETYLATION; ROOM-TEMPERATURE; ALCOHOLS; ACYLATION; AMINES; ACID;

D O I：

10.1080/00397911.2018.1459721

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The acetylation of phenols with acetic anhydride was achieved using a catalytic amount of magnesium metal powder under air and solvent-free conditions to afford corresponding phenyl acetates in excellent yield (up to 98%). [GRAPHICS] .

引用

页码：1688 / 1693

页数：6

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