Recent progress of transition metal based catalysts for the selective dimerization of ethylene

被引:35
作者
Bryliakov, Konstantin P. [1 ,2 ]
Antonov, Artem A. [1 ,2 ]
机构
[1] Boreskov Inst Catalysis, Pr Lavrentieva 5, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Pirogova 2, Novosibirsk 630090, Russia
关键词
Ethylene; 1-Butene; 2-Butene; Dimerization; Single-site; Transition metals; TRIDENTATE PYRAZOLYL LIGANDS; S-DONOR GROUPS; NICKEL-COMPLEXES; (IMIDO)VANADIUM(V) COMPLEXES; STRUCTURAL-CHARACTERIZATION; NI(II) COMPLEXES; ALPHA-OLEFINS; OLIGOMERIZATION; 1-BUTENE; TRIMERIZATION;
D O I
10.1016/j.jorganchem.2018.03.021
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this mini-review, the state-of-the-art of transition metal catalyzed selective dimerization of ethylene to butenes is presented. Catalytic activities, operating conditions, as well as the C-4 and 1-butene/cis- and trans-2-butene selectivities, are discussed. The scope of the review is 2000-present. (c) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:55 / 61
页数:7
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