Mesoporous biochar derived from silkworm excrement for high-performance supercapacitors

被引:11
作者
Zhang, Xiaozhan [1 ]
Wang, Zhenyu [1 ]
Dang, Guoju [1 ]
Zhang, Daoming [1 ]
Zhou, Dunfan [1 ]
Fan, Yaping [1 ]
Yu, Meng [1 ]
Zhang, Quansheng [1 ]
Xie, Jingying [2 ]
机构
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China
[2] Shanghai Inst Space Power Sources, Shanghai 200245, Peoples R China
关键词
supercapacitors; silkworm excrement; Mesoporous; higher specific surface; HIERARCHICAL POROUS CARBON; BIOMASS CARBON; ELECTRODE MATERIALS; ACTIVATED CARBON; GROWTH; WASTE;
D O I
10.20964/2019.09.34
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this work, Preparation of mesoporous carbon materials (Original-SE) by high temperature carbonization of biomass materials derived from silkworm has been successfully fabricated as high-performance and wide potential window electrodes for supercapacitors. pickling mesoporous carbon materials (Pickling-SE) are obtained from mesoporous carbon materials (Original-SE) via chemical (HCL) method. It is interesting that the pickling mesoporous carbon materials possesses a higher specific surface area of 293.97 m(2)/g than that of 112.64 m(2)/g for mesoporous carbon materials. A more excellent electrochemical performance of a specific capacitance of 291.5 F/g for Pickling-SE electrodes than that 208.3 F/g for Original-SE electrodes at 1A/g in 1M Li2SO4 electrolyte, and a higher stability for Pickling-SE electrodes (97.2%) than Original-SE electrodes (91.1%) over 5000 cycles.
引用
收藏
页码:8793 / 8804
页数:12
相关论文
共 42 条
[1]   Transformation of biomass into carbon nanofiber for supercapacitor application - A review [J].
Azwar, Elfina ;
Wan Mahari, Wan Adibah ;
Chuah, Joon Huang ;
Vo, Dai-Viet N. ;
Ma, Nyuk Ling ;
Lam, Wei Haur ;
Lam, Su Shiung .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (45) :20811-20821
[2]   Preparation of oxygen-rich hierarchical porous carbon for supercapacitors through the co-carbonization of pitch and biomass [J].
Cao, Shuo ;
Yang, Jianxiao ;
Li, Jun ;
Shi, Kui ;
Li, Xuanke .
DIAMOND AND RELATED MATERIALS, 2019, 96 :118-125
[3]   Hierarchical porous activated carbon for supercapacitor derived from corn stalk core by potassium hydroxide activation [J].
Cao, Yuhe ;
Wang, Keliang ;
Wang, Xiaomin ;
Gu, Zhengrong ;
Fan, Qihua ;
Gibbons, William ;
Hoefelmeyer, James D. ;
Kharel, Parashu Ram ;
Shrestha, Maheshwar .
ELECTROCHIMICA ACTA, 2016, 212 :839-847
[4]   MnO2/CdS/N-doped Graphite Nanocomposite for High Performance Supercapacitors [J].
Chen, Liang ;
Zuo, Yinze ;
Zhang, Yu ;
Gao, Yanmin .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2018, 13 (01) :642-654
[5]   Preparation of nitrogen doped clews-like carbon materials and their application as the electrode in supercapacitor [J].
Chen, Shengrui ;
Liang, Jiyuan ;
Zhao, Jinxing ;
Li, Haifeng ;
Liu, Yan ;
Deng, Heming ;
Liu, Chang ;
Tang, Shun ;
Cao, Yuan-Cheng .
CHINESE CHEMICAL LETTERS, 2019, 30 (03) :787-791
[6]  
Cherry R.H., 1987, Bulletin of the Entomological Society of America, V33, P83
[7]   Designing synthesis of porous biomass carbon from wheat straw and the functionalizing application in flexible, all-solid-state supercapacitors [J].
Du, Weimin ;
Zhang, Zirui ;
Du, Lange ;
Fan, Xiaoyang ;
Shen, Zhiwen ;
Ren, Xiaorui ;
Zhao, Yunpeng ;
Wei, Chengzhen ;
Wei, Shaohong .
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 797 (1031-1040) :1031-1040
[8]   Silkworms' feces-based activated carbons as cheap adsorbents for removal of cadmium and methylene blue from aqueous solutions [J].
ElShafei, Gamal M. S. ;
ElSherbiny, Ibrahim M. A. ;
Darwish, Atef S. ;
Philip, Christine A. .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2014, 92 (03) :461-470
[9]   Hollow carbon spheres/hollow carbon nanorods composites as electrode materials for supercapacitor [J].
Fu, Xinyu ;
Liu, Lei ;
Yu, Yifeng ;
Lv, Haijun ;
Zhang, Yue ;
Hou, Senlin ;
Chen, Aibing .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2019, 101 :244-250
[10]   Thermal Stability of [Ni(htde)](ClO4)2 and Its Corrosion Inhibition Effect for Mild Steel in 1.0 M HCl and H2SO4 Solutions [J].
Gou, Wan ;
Xie, Bin ;
Xu, Chong ;
Zheng, Zhi ;
He, Jiajun ;
Huang, Dan ;
Geng, Na .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2019, 14 (01) :494-505