Synthesis of Metal Organic Frameworks by Ball-Milling

被引：61
作者：
Tao, Cheng-An [1 ]
Wang, Jian-Fang [1 ]
机构：
[1] Natl Univ Def Technol, Coll Liberal Arts & Sci, Changsha 410073, Peoples R China
来源：
CRYSTALS | 2021年 / 11卷 / 01期
基金：
中国国家自然科学基金;
关键词：
metal organic framework; ball milling; grinding; neat grinding; liquid-assisted grinding; ion liquid-assisted grinding;
D O I：
10.3390/cryst11010015
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Metal-organic frameworks (MOFs) have been used in adsorption, separation, catalysis, sensing, photo/electro/magnetics, and biomedical fields because of their unique periodic pore structure and excellent properties and have become a hot research topic in recent years. Ball milling is a method of small pollution, short time-consumption, and large-scale synthesis of MOFs. In recent years, many important advances have been made. In this paper, the influencing factors of MOFs synthesized by grinding were reviewed systematically from four aspects: auxiliary additives, metal sources, organic linkers, and reaction specific conditions (such as frequency, reaction time, and mass ratio of ball and raw materials). The prospect for the future development of the synthesis of MOFs by grinding was proposed.
引用
收藏
页码：1 / 20
页数：20
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