Ion-selective gel that is sensitive to temperature, pH, and redox reactions

被引:8
作者
Bromberg, L [1 ]
Levin, G [1 ]
机构
[1] WEIZMANN INST SCI,DEPT MAT & INTERFACES,IL-76100 REHOVOT,ISRAEL
关键词
D O I
10.1002/marc.1996.030170303
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this communication we describe ion-selective poly[N,N-diethylacrylamide-co-(2-hydroxyethyl methacrylate)] gels functionalized by dialkyldithiophosphate group due to ester exchange reaction with the HEMA moieties. The gels are sensitive to temperature and pH in the surrounding aqueous solutions. Redox reactions cause gels to shrink due to crosslinking via disulfide bond formation.
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页码:169 / 172
页数:4
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