Preparation and characterization of [H3N(CH2)6NH3]PbI4 and similar compounds with a layered perovskite structure

被引：80
作者：
Mousdis, GA
Papavassiliou, GC
Raptopoulou, CP
Terzis, A
机构：
[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece
[2] NCSR Demokritos, Inst Mat Sci, GR-15310 Athens, Greece
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2000年 / 10卷 / 02期
关键词：
D O I：
10.1039/a906161d
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The preparation, crystal structure and optical absorption spectra of [H3N(CH2)(6)NH3]PbX4 (X = I, Br, Cl) and similar compounds based on Sn are described. The compounds [H3N(CH2)(6)NH3]PbX4 consist of ordered perovskite sheets of the corresponding-corner sharing PbX6 octahedra, which alternate with the H3N(CH2)(6)NH3 sheets. The excitonic peaks in the optical absorption spectra of these compounds occur at shorter wavelengths than those of the corresponding compounds with the formula [C6H5CH2CH2NH3](2)MX4.
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页码：515 / 518
页数：4
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