Physico-chemical modifications induced in Makrofol-N polycarbonate by swift heavy ions

被引:23
|
作者
Kumar, Rajesh [1 ]
Virk, H. S.
Verma, K. C.
De, Udayan
Saha, A.
Prasad, Rajendra
机构
[1] Aligarh Muslim Univ, ZH Coll Engn & Technol, Dept Appl Phys, Aligarh 202002, Uttar Pradesh, India
[2] Variable Energy Cyclotron Ctr, Kolkata 700064, W Bengal, India
[3] UGC DAE Consortium Sci Res, Kolkata 700098, W Bengal, India
关键词
Makrofol-N polycarbonate; C5+ ion irradiation; ion beam modification; FTIR; UV-Vis; differential scanning calorimetry;
D O I
10.1016/j.nimb.2006.06.003
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Optical, chemical and thermal properties of the polymers can be modified by swift heavy ion (SHI) irradiation. Fifty microns thick films of Makrofol-N were irradiated with 70 MeV C5+ ions to the fluences of 10(7), 10(8) and 9.3 x 10(11) and 9.3 x 10(12) ions/cm(2) from Pelletron accelerator at Nuclear Science Centre, New Delhi, India. The characterization of the radiation induced modifications has been carried out with FTIR, UV-Vis and differential scanning calorimetry (DSC). No change has been observed at lower fluences of 10(7) and 10(8) ions/cm(2). At higher fluences, slight shift in the optical absorption edge towards the red end of the spectrum has been observed with increase in fluence. FTIR and thermal data show changes at higher fluences. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:163 / 166
页数:4
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