Cooperative effects at the interface of nanocrystalline metal-organic frameworks

被引:51
作者
Rungtaweevoranit, Bunyarat [1 ]
Zhao, Yingbo [1 ]
Choi, Kyung Min
Yaghi, Omar M. [1 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
metal-organic framework; inorganic nanocrystal; cooperative effects; interface design; POROUS COORDINATION POLYMERS; HETEROGENEOUS CATALYSTS; MODULATED SYNTHESIS; PD NANOPARTICLES; LIGHT-SCATTERING; CRYSTAL-GROWTH; GOLD NANORODS; AT-MOF; SHELL; CORE;
D O I
10.1007/s12274-015-0970-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Controlling the chemistry at the interface of nanocrystalline solids has been a challenge and an important goal to realize desired properties. Integrating two different types of materials has the potential to yield new functions resulting from cooperative effects between the two constituents. Metal-organic frameworks (MOFs) are unique in that they are constructed by linking inorganic units with organic linkers where the building units can be varied nearly at will. This flexibility has made MOFs ideal materials for the design of functional entities at interfaces and hence allowing control of properties. This review highlights the strategies employed to access synergistic functionality at the interface of nanocrystalline MOFs (nMOFs) and inorganic nanocrystals (NCs).
引用
收藏
页码:47 / 58
页数:12
相关论文
共 46 条
[1]   Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal-Organic Framework: A Double Solvents Approach [J].
Aijaz, Arshad ;
Karkamkar, Abhi ;
Choi, Young Joon ;
Tsumori, Nobuko ;
Roennebro, Ewa ;
Autrey, Tom ;
Shioyama, Hiroshi ;
Xu, Qiang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (34) :13926-13929
[2]   Metal-organic framework encapsulated Pd nanoparticles: towards advanced heterogeneous catalysts [J].
Chen, Liyu ;
Chen, Huirong ;
Luque, Rafael ;
Li, Yingwei .
CHEMICAL SCIENCE, 2014, 5 (10) :3708-3714
[3]   Chemical Environment Control and Enhanced Catalytic Performance of Platinum Nanoparticles Embedded in Nanocrystalline Metal-Organic Frameworks [J].
Choi, Kyung Min ;
Na, Kyungsu ;
Somorjai, Gabor A. ;
Yaghi, Omar M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (24) :7810-7816
[4]   Supercapacitors of Nanocrystalline Metal-Organic Frameworks [J].
Choi, Kyung Min ;
Jeong, Hyung Mo ;
Park, Jung Hyo ;
Zhang, Yue-Biao ;
Kang, Jeung Ku ;
Yaghi, Omar M. .
ACS NANO, 2014, 8 (07) :7451-7457
[5]   Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering [J].
Cravillon, Janosch ;
Nayuk, Roman ;
Springer, Sergej ;
Feldhoff, Armin ;
Huber, Klaus ;
Wiebcke, Michael .
CHEMISTRY OF MATERIALS, 2011, 23 (08) :2130-2141
[6]   A new method to position and functionalize metal-organic framework crystals [J].
Falcaro, Paolo ;
Hill, Anita J. ;
Nairn, Kate M. ;
Jasieniak, Jacek ;
Mardel, James I. ;
Bastow, Timothy J. ;
Mayo, Sheridan C. ;
Gimona, Michele ;
Gomez, Daniel ;
Whitfield, Harold J. ;
Ricco, Raffaele ;
Patelli, Alessandro ;
Marmiroli, Benedetta ;
Amenitsch, Heinz ;
Colson, Tobias ;
Villanova, Laura ;
Buso, Dario .
NATURE COMMUNICATIONS, 2011, 2
[7]   Synthetic routes toward MOF nanomorphologies [J].
Fluegel, Erik A. ;
Ranft, Annekathrin ;
Haase, Frederik ;
Lotsch, Bettina V. .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (20) :10119-10133
[8]   Functional Hybrid Porous Coordination Polymers [J].
Foo, Maw Lin ;
Matsuda, Ryotaro ;
Kitagawa, Susumu .
CHEMISTRY OF MATERIALS, 2014, 26 (01) :310-322
[9]   "Heterogeneity within Order" in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Mueller, Ulrich ;
Yaghi, Omar M. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (11) :3417-3430
[10]   The Chemistry and Applications of Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Cordova, Kyle E. ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2013, 341 (6149) :974-+